Study of Hydrate Particle Morphology and Cohesive Force in the Presence of Wax and Glycine
文献类型：期刊论文
| 作者 | Zhou, Shi-dong1; Ren, Zhen-hao1; Yu, Yi-song2; Liu, Yang1; Lv, Xiao-fang1; Du, Hui1 |
| 刊名 | ENERGY & FUELS
 |
| 出版日期 | 2024-03-08 |
| 卷号 | 38期号:6页码:5064-5074 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.4c00237 |
| 通讯作者 | Zhou, Shi-dong(zsd@cczu.edu.cn) |
| 英文摘要 | During the operation of deep-sea pipelines, the accumulation and deposition of hydrates are important reasons for pipeline blockage. The current main measure to solve the hydrate plugging problem is the addition of low-dose inhibitors (LDHIs), but it is not yet known whether the precipitation of wax crystals will affect their effectiveness. Therefore, in this study, the hydrate cohesive force within the wax-free/wax-containing system was directly measured by using a micromechanical force device (MMF) and the reasons for the change in cohesive force were analyzed from a morphological point of view. The results showed that glycine was effective in reducing the cohesion between hydrate particles in both wax-free/wax-containing systems and still exerted the effect of antiagglomeration agent (AA) at very low concentrations (as low as 0.10 wt %). Moreover, the optimum concentration of glycine was 0.50 wt %. At this concentration, the cohesive force decreased from 8.54 to 7.07 mN/m in the wax-free system, a decrease of about 17.2%, while the cohesive force decreased from 5.94 to 2.15 mN/m in the wax-containing system, a decrease of about 63.8%. By observation of the morphology of the hydrate particles, the presence of glycine was found to reduce the volume of the liquid bridge by changing the surface roughness and wettability of the particles, thereby reducing the cohesive force. And when wax was contained in the system, the wax further reduced the wettability by adsorbing on the surface of the hydrate particles. However, under certain AA conditions, the increase in wax concentration (from 0.1 to 0.3 wt %) resulted in the free water inside the hydrate being more likely to form liquid bridges with the surrounding particles, thus weakening the effect of AA. This work analyzes the effect on cohesive force in the simultaneous presence of LDHIs and wax from a morphological point of view, which is beneficial in providing more insights into securing safe hydrate flow management. |
| WOS关键词 | ANTI-AGGLOMERANT ; ADHESION FORCE ; OIL ; GROWTH ; SURFACTANT ; SLURRY |
| 资助项目 | China National Petroleum Corporation[51974037] ; China National Petroleum Corporation[52004039] ; China National Petroleum Corporation[52274061] ; National Natural Science Foundation of China[2022DQ02-0501] ; CNPC Innovation Found |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001181870500001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | China National Petroleum Corporation ; National Natural Science Foundation of China ; CNPC Innovation Found |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41199]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhou, Shi-dong |
| 作者单位 | 1.Changzhou Univ, Jiangsu Key Lab Oil & Gas Storage & Transportat Te, Changzhou 213016, Jiangsu, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Shi-dong,Ren, Zhen-hao,Yu, Yi-song,et al. Study of Hydrate Particle Morphology and Cohesive Force in the Presence of Wax and Glycine[J]. ENERGY & FUELS,2024,38(6):5064-5074. |
| APA | Zhou, Shi-dong,Ren, Zhen-hao,Yu, Yi-song,Liu, Yang,Lv, Xiao-fang,&Du, Hui.(2024).Study of Hydrate Particle Morphology and Cohesive Force in the Presence of Wax and Glycine.ENERGY & FUELS,38(6),5064-5074. |
| MLA | Zhou, Shi-dong,et al."Study of Hydrate Particle Morphology and Cohesive Force in the Presence of Wax and Glycine".ENERGY & FUELS 38.6(2024):5064-5074. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。