Enhancing solar energy utilization: A red-emitting Sr2In0.5Sb0.5O4:Mn4+ phosphor with both UV and green excitation for plant growth
文献类型：期刊论文
| 作者 | Shan, Kaian1; Jing, Baolong1,2; Han, Jin1,2; Fei, Huihui1; Zhou, Yuhang1; Xu, Xueqing2; Zhang, Xinmin1 |
| 刊名 | JOURNAL OF LUMINESCENCE
 |
| 出版日期 | 2024-05-01 |
| 卷号 | 269页码:8 |
| 关键词 | Red light Phosphor Crystal structure Mn4+ luminescence Plant growth |
| ISSN号 | 0022-2313 |
| DOI | 10.1016/j.jlumin.2024.120528 |
| 通讯作者 | Han, Jin(hanjin@csuft.edu.cn) ; Xu, Xueqing(xuxq@ms.giec.ac.cn) ; Zhang, Xinmin(zhangxm@csuft.edu.cn) |
| 英文摘要 | Red light in sunlight promotes plant growth and development, while UV and green light are poorly absorbed by plants. Converting UV and green light into red light can enhance solar energy utilization and improve photosynthetic efficiency, significantly shortening the plant growth cycle. Herein, we report a novel red-emitting Sr2In0.5Sb0.5O4:Mn4+ phosphor that can be effectively excited by both UV and green light. According to Dexter's theory, Mn4+ is calculated to be in a weak crystal field. When excited at 330 or 520 nm, the characteristic photoluminescence (PL) peak appears at similar to 695 nm, which is attributed T-4(2g) -> (4)A(2g) transition of Mn4+. The optimal doping concentration of Mn4+ is 0.003, and the concentration quenching mechanism was determined to be a dipole-dipole interaction. Additionally, a red LED device was fabricated by encapsulating Sr2In0.5Sb0.497O4:0.003Mn(4+) phosphor with a 365 nm UV chip, exhibiting bright red light when driven by 150 mA current. The corresponding electroluminescence (EL) spectrum matches well with the absorption spectra of phytochromes P-R and P-FR, indicating that Sr2In0.5Sb0.5O4:Mn4+ phosphor has promising applications in plant growth. |
| WOS关键词 | DOUBLE-PEROVSKITE STRUCTURE ; CRYSTAL-STRUCTURE ; LEDS SYNTHESIS ; LUMINESCENCE ; IONS |
| 资助项目 | Hunan Provincial Natural Science Foundation[2020JJ5983] ; Scientific Research Fund of Human Provincial Education Department[23C0106] |
| WOS研究方向 | Optics |
| 语种 | 英语 |
| WOS记录号 | WOS:001203085500001 |
| 出版者 | ELSEVIER |
| 资助机构 | Hunan Provincial Natural Science Foundation ; Scientific Research Fund of Human Provincial Education Department |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41403]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Han, Jin; Xu, Xueqing; Zhang, Xinmin |
| 作者单位 | 1.Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Hunan Prov Key Lab Mat Surface & Interface Sci & T, Changsha 410004, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shan, Kaian,Jing, Baolong,Han, Jin,et al. Enhancing solar energy utilization: A red-emitting Sr2In0.5Sb0.5O4:Mn4+ phosphor with both UV and green excitation for plant growth[J]. JOURNAL OF LUMINESCENCE,2024,269:8. |
| APA | Shan, Kaian.,Jing, Baolong.,Han, Jin.,Fei, Huihui.,Zhou, Yuhang.,...&Zhang, Xinmin.(2024).Enhancing solar energy utilization: A red-emitting Sr2In0.5Sb0.5O4:Mn4+ phosphor with both UV and green excitation for plant growth.JOURNAL OF LUMINESCENCE,269,8. |
| MLA | Shan, Kaian,et al."Enhancing solar energy utilization: A red-emitting Sr2In0.5Sb0.5O4:Mn4+ phosphor with both UV and green excitation for plant growth".JOURNAL OF LUMINESCENCE 269(2024):8. |
入库方式： OAI收割
来源：广州能源研究所
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