Metal Organic Frameworks as Polysulfide Reaction Modulators for Lithium Sulfur Batteries: Advances and Perspectives
文献类型：期刊论文
| 作者 | Fan, Xuliang5; Zhang, You4; Peng, Ruosi4; Liang, Zheng2; Zhou, Xunfu5; Luo, Xiaonan5; Chen, Rong4; Li, Ping1; Yu, Dingshan3 |
| 刊名 | CHEMPHYSCHEM
 |
| 出版日期 | 2024-05-14 |
| 页码 | 16 |
| 关键词 | metal organic frameworks lithium sulfur battery polysulfides adsorption electrocatalysis |
| ISSN号 | 1439-4235 |
| DOI | 10.1002/cphc.202400239 |
| 通讯作者 | Zhang, You(zhangyou@dgut.edu.cn) ; Yu, Dingshan(yudings@mail.sysu.edu.cn) |
| 英文摘要 | Currently, lithium sulfur (Li-S) battery with high theoretical energy density has attracted great research interest. However, the diffusion and loss process of intermediate lithium polysulfide during charge-discharge hindered the application of the Li-S battery in modern life. To overcome this issue, metal organic frameworks (MOFs) and their composites have been regarded as effective additions to restrain the LiPS diffusion process for Li-S battery. Benefiting from the unique structure with rich active sites to adsorb LiPS and accelerate the LiPS redox, the Li-S batteries with MOFs modified exhibit superior electrochemical performance. Considering the rapid development of MOFs in Li-S battery, this review summarizes the recent studies of MOFs and their composites as the sulfur host materials, functional interlayer, separator coating layer, and separator/solid electrolyte for Li-S batteries in detail. In addition, the promising design strategies of functional MOF materials are proposed to improve the electrochemical performance of Li-S battery. MOFs have shown great application prospect for restricting LiPS diffusion owing to their abundant pores and catalytic active sites. Considering the rapid development of MOFs in Li-S batteries, this review summarizes the mechanisms and applications of MOFs in Li-S batteries systematically and proposes the development direction precisely, which could support the preparation of high-efficiency MOFs for advanced Li-S batteries. image |
| WOS关键词 | CARBON ; PERFORMANCE ; SEPARATOR ; STRATEGY ; MOF |
| 资助项目 | Guangdong Basic and Applied Basic Research Foundation ; Scientific Research Foundation for Introduce Talent by Dongguan University of Technology[GC300501-127] ; Science and Technology planning Project of Zhanjiang[2021A05027] ; National Natural Science Foundation of China[52203253] ; Natural Science Foundation of Chongqing[CSTB2022NSCQ-MSX1178] ; Scientific and Technological Research Program of Chongqing Municipal Education Commission[KJQN202201534] ; [2019A1515110826] ; [2019A1515110646] |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001221746600001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | Guangdong Basic and Applied Basic Research Foundation ; Scientific Research Foundation for Introduce Talent by Dongguan University of Technology ; Science and Technology planning Project of Zhanjiang ; National Natural Science Foundation of China ; Natural Science Foundation of Chongqing ; Scientific and Technological Research Program of Chongqing Municipal Education Commission |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41694]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, You; Yu, Dingshan |
| 作者单位 | 1.Chongqing Univ Sci & Technol, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Sun Yat sen Univ, Sch Chem, Key Lab Polymer Composite & Funct Mat, Minist Educ,Key Lab High Performance Polymer based, Guangzhou 510006, Peoples R China 4.Dongguan Univ Technol, Sch Environm & Civil Engn, Dongguan 523808, Peoples R China 5.Lingnan Normal Univ, Key Lab Clean Energy Mat Chem, Res Ctr Clean Energy Mat Chem Engn Technol Guangdo, Guangdong Higher Educ Inst,Sch Chem & Chem Engn,In, Zhanjiang 524048, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Xuliang,Zhang, You,Peng, Ruosi,et al. Metal Organic Frameworks as Polysulfide Reaction Modulators for Lithium Sulfur Batteries: Advances and Perspectives[J]. CHEMPHYSCHEM,2024:16. |
| APA | Fan, Xuliang.,Zhang, You.,Peng, Ruosi.,Liang, Zheng.,Zhou, Xunfu.,...&Yu, Dingshan.(2024).Metal Organic Frameworks as Polysulfide Reaction Modulators for Lithium Sulfur Batteries: Advances and Perspectives.CHEMPHYSCHEM,16. |
| MLA | Fan, Xuliang,et al."Metal Organic Frameworks as Polysulfide Reaction Modulators for Lithium Sulfur Batteries: Advances and Perspectives".CHEMPHYSCHEM (2024):16. |
入库方式： OAI收割
来源：广州能源研究所
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