Boosted charge separation via Ce2S3 over dual Z-scheme ZnO-Ce2S3-MnO2 core double-shell nanocomposite for the degradation of diverse dye pollutants
文献类型：期刊论文
| 作者 | Munawar, Tauseef5; Alomar, Taghrid S.4; Yan, Chang-Feng5; Fatima, Saman3; Mukhtar, Faisal3; Nadeem, Muhammad Shahid3; Almasoud, Najla4; Khan, Shoukat Alim2; Koc, Muammer2; Zakaria, Yahya1 |
| 刊名 | ENVIRONMENTAL RESEARCH
 |
| 出版日期 | 2024-06-15 |
| 卷号 | 251页码:15 |
| 关键词 | Core double-shell Dual-phase Z-scheme Charge separation Hydrothermal Pollutant dyes |
| ISSN号 | 0013-9351 |
| DOI | 10.1016/j.envres.2024.118675 |
| 通讯作者 | Yan, Chang-Feng(yancf@ms.giec.ac.cn) ; Iqbal, Faisal(faisal.iqbal@iub.edu.pk) |
| 英文摘要 | Herein, core double-shell direct dual Z-scheme ZnO-Ce2S3-MnO2 nanocomposite was synthesized via a hydrothermal route along with pure ZnO, Ce2S3, MnO2, and characterized by numerous characterization tools for application in synthetic dyes degradation. The XRD, Raman, and FTIR analyses have confirmed the nanocomposite formation. TEM images exhibited the core double-shell morphology with an average particle diameter of 81 nm and stacking of ZnO, Ce2S3, and MnO2. EDX confirmed the existence of desired elements in the grown composition. The varied oxidation states, presence of defects, and fast charge transfer were also revealed from XPS, PL, and EIS. The ZnO-Ce2S3-MnO2 nanocomposite has an optical energy bandgap of 2.84 eV, capable of decomposing harmful dyes with excellent efficiency, 99.81% MB, 97.62% MO, 88.5% MR, and 58.9% EY in 40 min sunlight exposure. The effect of several operating parameters is also observed and obtained results showed the optimal catalyst dose was 20 mg, pH of 8, and dye concentration of 10 ppm. The scavenger's experiment suggests that O-center dot(2)- and (OH)-O-center dot are the main active radicals in the photodegradation reaction which is also evident in the dual Z-scheme formation. The MnO2 and ZnO layers covered the Ce2S3 (core) and dual Z-scheme formation allows rapid kinetics of redox reaction and provides plenteous channels for transfer of photo-generated charge carriers during photocatalysis. Thus, core double-shell direct dual Z-scheme photocatalysts having inorganic components could be an excellent choice for photocatalysis at the industrial level, particularly for water purification. |
| WOS关键词 | PHOTOCATALYTIC ACTIVITY ; ZNO ; ELECTRODE ; FABRICATION ; COMPOSITES |
| 资助项目 | Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia[PNURSP2024R47] |
| WOS研究方向 | Environmental Sciences & Ecology ; Public, Environmental & Occupational Health |
| 语种 | 英语 |
| WOS记录号 | WOS:001221871800001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41765]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yan, Chang-Feng; Iqbal, Faisal |
| 作者单位 | 1.Hamad Bin Khalifa Univ, Qatar Fdn, Qatar Environm & Energy Res Inst, POB 34110, Doha, Qatar 2.Hamad Bin Khalifa Univ, Qatar Fdn, Coll Sci & Engn, Div Sustainable Dev, POB 34110, Doha, Qatar 3.Islamia Univ Bahawalpur, Inst Phys, Bahawalpur 63100, Pakistan 4.Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia 5.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Munawar, Tauseef,Alomar, Taghrid S.,Yan, Chang-Feng,et al. Boosted charge separation via Ce2S3 over dual Z-scheme ZnO-Ce2S3-MnO2 core double-shell nanocomposite for the degradation of diverse dye pollutants[J]. ENVIRONMENTAL RESEARCH,2024,251:15. |
| APA | Munawar, Tauseef.,Alomar, Taghrid S..,Yan, Chang-Feng.,Fatima, Saman.,Mukhtar, Faisal.,...&Iqbal, Faisal.(2024).Boosted charge separation via Ce2S3 over dual Z-scheme ZnO-Ce2S3-MnO2 core double-shell nanocomposite for the degradation of diverse dye pollutants.ENVIRONMENTAL RESEARCH,251,15. |
| MLA | Munawar, Tauseef,et al."Boosted charge separation via Ce2S3 over dual Z-scheme ZnO-Ce2S3-MnO2 core double-shell nanocomposite for the degradation of diverse dye pollutants".ENVIRONMENTAL RESEARCH 251(2024):15. |
入库方式： OAI收割
来源：广州能源研究所
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