From macro to micro: Biomass-derived advanced carbon microtube assembly for sodium-ion batteries
文献类型：期刊论文
| 作者 | Yang, Hui7,8; Yin, Jian5,6; Yang, Juntao4,7,8; Tang, Songbiao7,8; Zhang, Wenli1,2,3; Yang, Gaixiu7,8 |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2024-06-15 |
| 卷号 | 125页码:9 |
| 关键词 | Carbon anodes Microtubes Biomass Sodium-ion batteries Rate capability |
| ISSN号 | 2211-2855 |
| DOI | 10.1016/j.nanoen.2024.109591 |
| 通讯作者 | Zhang, Wenli(wlzhang@gdut.edu.cn) ; Yang, Gaixiu(yanggx@ms.giec.ac.cn) |
| 英文摘要 | Developing high-rate anode materials for sodium-ion batteries is important to fulfill the requirement of highpower energy storage applications. Amorphous carbon micro-tubes (CMTs) are favorable for fast Na-ion storage, for the open carbon framework provides sufficient electrode/electrolyte contact and the one-dimensional skeleton offers fast electron and ion diffusion pathways. Herein, N, Fe co-doped carbon micron-tubes (NFCMTs) were synthesized for the high-rate anode by using bulk biomass as the precursor. The transformation from the macro-sized biomass to the micro-sized carbon tubes was endowed by pyrolysis using N and Fe as catalysts. The open carbon frameworks enable capacitive-controlled capacity contribution, while its N-Fe defects offer multiple active sites for fast Na-ion storage. A high-capacity contribution was demonstrated by the pseudocapacitive mechanism so that the NF-CMTs performed a superior rate capability of 120 mAh g- 1 at 2.0 A g-1. The NF-CMTs with stable micro-tube frameworks exhibited high cycling stability over 1200 cycles, which was much superior to the commercial hard carbon anode. This study provides a cost-effective approach to develop carbon micro-tubes from bulk biomass for high-power SIB anodes. |
| WOS关键词 | GENERALIZED GRADIENT APPROXIMATION ; CAPACITY ANODE MATERIALS ; LITHIUM ; STORAGE ; STRATEGIES ; INSERTION ; SAFETY |
| 资助项目 | National Natural Science Foundation of China[52176214] ; National Key R & D Program of China[2022YFC3902400] ; Shenzhen Science and Technology Program[JCYJ20200109150210400] ; Youth Innovation Promotion Associa- tion CAS[2020345] ; Silk Road Economic Belt Innovation -driven Development Pilot Zone, Wuchangshi National Independent Innova- tion Demonstration Zone Science and Technology Development Plan of China[2023LQ04002] ; Open Foundation of Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Mo- lecular Engineering[JDSX2023002] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001227839200001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; National Key R & D Program of China ; Shenzhen Science and Technology Program ; Youth Innovation Promotion Associa- tion CAS ; Silk Road Economic Belt Innovation -driven Development Pilot Zone, Wuchangshi National Independent Innova- tion Demonstration Zone Science and Technology Development Plan of China ; Open Foundation of Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Mo- lecular Engineering |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41834]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Wenli; Yang, Gaixiu |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Shaoxing Res Inst Renewable Energy & Mol Engn, Shaoxing 312000, Peoples R China 2.Jieyang Ctr, Guangdong Prov Lab Chem & Fine Chem Engn, Jieyang 515200, Peoples R China 3.Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China 4.Shandong Univ Technol, Sch Agr Engn & Food Sci, Zibo 255000, Peoples R China 5.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China 6.King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, Mat Sci & Engn, Thuwal 239556900, Saudi Arabia 7.Univ Sci & Technol China USTC, Sch Engn Sci, Hefei 230026, Peoples R China 8.Chinese Acad Sci, CAS Key Lab Renewable Energy Guangdong Prov, Key Lab New & Renewable Energy Res & Dev, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hui,Yin, Jian,Yang, Juntao,et al. From macro to micro: Biomass-derived advanced carbon microtube assembly for sodium-ion batteries[J]. NANO ENERGY,2024,125:9. |
| APA | Yang, Hui,Yin, Jian,Yang, Juntao,Tang, Songbiao,Zhang, Wenli,&Yang, Gaixiu.(2024).From macro to micro: Biomass-derived advanced carbon microtube assembly for sodium-ion batteries.NANO ENERGY,125,9. |
| MLA | Yang, Hui,et al."From macro to micro: Biomass-derived advanced carbon microtube assembly for sodium-ion batteries".NANO ENERGY 125(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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