Selective hydrodeoxygenation of 5-hydromethylfurfural to 2,5-dimethylfuran over PtFe/C catalyst
文献类型：期刊论文
| 作者 | Huang, Zhijiao4,5; Liu, Yong1,2; Chen, Lungang3; Zhang, Xinghua3; Liu, Jianguo3; Wang, Chenguang4,5; Zhang, Qi3; Ma, Longlong3 |
| 刊名 | MOLECULAR CATALYSIS
 |
| 出版日期 | 2024-05-15 |
| 卷号 | 561页码:9 |
| 关键词 | Biomass Hydrodeoxygenation PtFe/C 5-hydroxymethylfurfural 5-dimethylfuran |
| ISSN号 | 2468-8231 |
| DOI | 10.1016/j.mcat.2024.114169 |
| 通讯作者 | Chen, Lungang(chenlg@seu.edu.cn) |
| 英文摘要 | 2,5-dimethylfuran (DMF), a promising biomass-derived fuel, is synthesized via the hydrodeoxygenation of 5hydroxymethylfurfural (HMF). This study focuses on the inherent activity of a 5Pt5Fe/C catalyst for HMF hydrodeoxygenation to DMF. The catalyst exhibited exceptional performance, achieving a remarkable DMF yield of 99.6 %. It displayed specific selectivity for C = O bond hydrogenation and C-O bond cleavage in diverse substrates, producing high yield of 2-methylfuran from furfural and furfury alcohol, and high yield of toluene from benzaldehyde, benzyl alcohol. In-depth characterizations unveiled valuable insights into the 5Pt5Fe/C catalyst's properties, emphasizing a harmonious balance between metal and acid sites due to the interactive synergy between Pt and Fe species, enhancing hydrodeoxygenation activity. Additionally, the catalyst demonstrated satisfactory stability, maintaining a commendable DMF yield over five reaction cycles despite observed changes. |
| WOS关键词 | LIQUID FUEL 2,5-DIMETHYLFURAN ; EFFICIENT PRODUCTION ; HYDROGENATION ; BIOMASS ; ACID ; CONVERSION ; OXIDATION ; ALKANES ; OXIDE ; RU |
| 资助项目 | National Natural Science Foundation of China[52236010] ; High Level Personnel Project of Jiangsu Province[JSSCBS20220085] ; Talent Program of Jiangxi Province of China[jxsq2020102023] ; Funda- mental Research Funds for the Central Universities[2242022R10058] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001236364400001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; High Level Personnel Project of Jiangsu Province ; Talent Program of Jiangxi Province of China ; Funda- mental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41885]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Chen, Lungang |
| 作者单位 | 1.Nanchang Univ, Minist Educ, Key Lab Poyang Lake Environm & Resource Utilizat, Nanchang 330031, Peoples R China 2.Nanchang Univ, Minist Educ, Sch Resources & Environm, Nanchang 330031, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Univ Sci & Technol China, Sch Energy Sci & Engn, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Zhijiao,Liu, Yong,Chen, Lungang,et al. Selective hydrodeoxygenation of 5-hydromethylfurfural to 2,5-dimethylfuran over PtFe/C catalyst[J]. MOLECULAR CATALYSIS,2024,561:9. |
| APA | Huang, Zhijiao.,Liu, Yong.,Chen, Lungang.,Zhang, Xinghua.,Liu, Jianguo.,...&Ma, Longlong.(2024).Selective hydrodeoxygenation of 5-hydromethylfurfural to 2,5-dimethylfuran over PtFe/C catalyst.MOLECULAR CATALYSIS,561,9. |
| MLA | Huang, Zhijiao,et al."Selective hydrodeoxygenation of 5-hydromethylfurfural to 2,5-dimethylfuran over PtFe/C catalyst".MOLECULAR CATALYSIS 561(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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