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Three-dimensional ordered FeTe-SmCoO3 nanocomposite: As efficient electrocatalyst for water oxidation

文献类型:期刊论文

作者Munawar, Tauseef8; Bashir, Ambreen7; El-Bahy, Salah M.6; Yan, Chang-Feng8; Khalid, Awais5; El-Bahy, Zeinhom M.4; Riaz, Nagina Naveed3; Mukhtar, Faisal7; Manzoor, Sumaira2; Khan, Shoukat Alim1
刊名JOURNAL OF ALLOYS AND COMPOUNDS
出版日期2024-08-15
卷号995页码:13
关键词Transition metal chalcogenide FeTe-SmCoO 3 Heterogeneous electrocatalyst SS substrate Electrochemical oxygen evolution
ISSN号0925-8388
DOI10.1016/j.jallcom.2024.174747
通讯作者Yan, Chang-Feng(yancf@ms.giec.ac.cn) ; Iqbal, Faisal(faisal.iqbal@iub.edu.pk)
英文摘要In this work, FeTe-SmCoO3 is fabricated through a hydrothermal method and then coated on a stainless steel (SS) substrate to enhance the electrocatalytic performance. The crystal structure, surface chemical state, and morphological features of pure (FeTe and SmCoO3) and heterogeneous catalysts (FeTe-SmCoO3) are determined via XRD, XPS, and TEM/EDX techniques. The fabricated FeTe-SmCoO3 electrocatalyst is attributed to the particular morphological design resulting from the synergistic effect of FeTe and SmCoO3 phases. The asdeveloped high exposure level of active sites with structural transformation greatly promoted the oxidation property with an overpotential only of 199 mV to derive a current density of 10 mA/cm2, also observed a small Tafel slope of 72 mVdec- 1 with extraordinary stability of 90 h. The modified heterogeneous catalyst provides outstanding catalytic behavior toward OER in the alkaline solution, due to flexibility and multiple accessible oxidation states of samarium, cobalt, and iron ions. The catalyst not only acquires additional reaction sites and opens up new channels through the dispersion of the metal centers, but also achieves quick electron transfer in FeTe-SmCoO3 nanocomposite through the interconnection between two phases.
WOS关键词CARBON-PASTE ELECTRODE ; OXYGEN EVOLUTION REACTION ; SURFACE ; CATALYSTS ; CO3O4
资助项目Taif University, Saudi Arabia[TU-DSPP- 2024-20]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:001240837800001
出版者ELSEVIER SCIENCE SA
资助机构Taif University, Saudi Arabia
源URL[http://ir.giec.ac.cn/handle/344007/42006]  
专题中国科学院广州能源研究所
通讯作者Yan, Chang-Feng; Iqbal, Faisal
作者单位1.Hamad Bin Khalifa Univ, Qatar Fdn, Coll Sci & Engn, Div Sustainable Dev, Doha, Qatar
2.King Fahd Univ Petr & Minerals, Interdisciplinary Res Ctr Hydrogen Technol & Carbo, Dhahran 31261, Saudi Arabia
3.Univ Educ, Dept Chem, Div Sci & Technol, Vehari Campus, Lahore, Pakistan
4.Al Azhar Univ Nasr City, Fac Sci, Dept Chem, Cairo 11884, Egypt
5.Prince Sattam Bin Abdulaziz Univ, Dept Phys, Coll Sci & Humanities, Al Kharj 11942, Saudi Arabia
6.Taif Univ, Turabah Univ Coll, Dept Chem, POB 11099, Taif 21944, Saudi Arabia
7.Islamia Univ Bahawalpur, Inst Phys, Bahawalpur 63100, Pakistan
8.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714
Munawar, Tauseef,Bashir, Ambreen,El-Bahy, Salah M.,et al. Three-dimensional ordered FeTe-SmCoO3 nanocomposite: As efficient electrocatalyst for water oxidation[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2024,995:13.
APA Munawar, Tauseef.,Bashir, Ambreen.,El-Bahy, Salah M..,Yan, Chang-Feng.,Khalid, Awais.,...&Iqbal, Faisal.(2024).Three-dimensional ordered FeTe-SmCoO3 nanocomposite: As efficient electrocatalyst for water oxidation.JOURNAL OF ALLOYS AND COMPOUNDS,995,13.
MLA Munawar, Tauseef,et al."Three-dimensional ordered FeTe-SmCoO3 nanocomposite: As efficient electrocatalyst for water oxidation".JOURNAL OF ALLOYS AND COMPOUNDS 995(2024):13.

入库方式: OAI收割

来源:广州能源研究所

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