Facile synthesis of tetrahydrocarbazoles under photocatalyst-free conditions
文献类型：期刊论文
| 作者 | Jiang, Dong-Xiao; Chen, Zhang; Shu, Qing; Tan, Yufeng; Chen, Jinjin; Zhang, Xi; Lei, Zhengwen; Wang, Zhen; Zeng, Yao-Fu |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2025 |
| 卷号 | 23期号:40页码:9094 |
| 英文摘要 | Herein, we report a visible-light-induced, photocatalyst-free protocol for the preparation of tetrahydrocarbazoles via cascade decarboxylative cyclization of indolyl NHPI esters with alkenes. This approach features a broad substrate scope and eliminates the need for photocatalysts, distinguishing it from prior methods. Tetrahydrodibenzo[b,d]furan and tetrahydrodibenzo[b,d]thiophene could also be obtained under the standard conditions. Preliminary mechanistic studies indicate that an EDA complex formation from KI, PPh3 and NHPI esters facilitates the reaction. The synthetic utility of this method was further demonstrated through post-transformation of the products. |
| 源URL | [http://210.75.249.4/handle/363003/62362]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Jiang, Dong-Xiao,Chen, Zhang,Shu, Qing,et al. Facile synthesis of tetrahydrocarbazoles under photocatalyst-free conditions[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2025,23(40):9094. |
| APA | Jiang, Dong-Xiao.,Chen, Zhang.,Shu, Qing.,Tan, Yufeng.,Chen, Jinjin.,...&Zeng, Yao-Fu.(2025).Facile synthesis of tetrahydrocarbazoles under photocatalyst-free conditions.ORGANIC & BIOMOLECULAR CHEMISTRY,23(40),9094. |
| MLA | Jiang, Dong-Xiao,et al."Facile synthesis of tetrahydrocarbazoles under photocatalyst-free conditions".ORGANIC & BIOMOLECULAR CHEMISTRY 23.40(2025):9094. |
入库方式： OAI收割
来源：西北高原生物研究所
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