Controllable preparation of Co-based catalysts doped with Cu and Mo for boosting hydrogen evolution
文献类型：期刊论文
| 作者 | Liu, Junhui2; Li, Mengting2; Zhang, Wenke2; Li, Xiang3; Zhao, Yuan2; Zhu, Chunyou1; Li, Shikun4 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2024-10-25 |
| 卷号 | 1003页码:9 |
| 关键词 | Hydrogen generation Ammonia borane ZIF-derived materials Co-based catalyst |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2024.175629 |
| 通讯作者 | Li, Xiang(lixiang@haust.edu.cn) ; Li, Shikun(shikunli@xju.edu.cn) |
| 英文摘要 | Hydrogen evolution from ammonia borane hydrolysis is a promising way for utilization of clean energy. Development of efficient and stable non-noble catalysts for improvement of hydrogen generation rate is essential but still a challenge. Herein, the heterostructured Co-based catalysts were controllably designed by combining the synergistic effect with oxygen vacancy engineering to improve the hydrogen generation rate. CoCu1Mo3-NCO-15 exhibits the TOF value of 24.44 min- 1 at 298 K with addition of 0.44 M NaOH, which is nearly 68 times that of Co-NC. The activation energy over CoCu1Mo3-NC-O-15 is 28.44 kJ mol-1. The CoCu1Mo3-NC-O-15 catalyst presents the good stability in ammonia borane hydrolysis reaction due to the carbon-coated structure. The strong synergistic effect and oxygen vacancy are favorable to the adsorption and dissociation of NH3BH3 and H2O molecules, leading to an astonishing improvement of catalytic activity. This study provides a novel way to design the heterostructured catalysts and a rational way to boost the dehydrogenation rate from AB. |
| WOS关键词 | HYDROLYTIC DEHYDROGENATION ; AMMONIA BORANE ; MESOPOROUS CARBON ; EFFICIENT ; NANOPARTICLES ; NANOCLUSTERS ; NANOTUBES ; INSIGHT |
| 资助项目 | Natural Science Foundation of Henan Province[242300421619] ; National Nat-ural Science Foundation of China[42307285] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515110525] ; Fundamental Research Funds for the Universities of Xinjiang[202403120001] |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001278354000001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Natural Science Foundation of Henan Province ; National Nat-ural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; Fundamental Research Funds for the Universities of Xinjiang |
| 源URL | [http://ir.giec.ac.cn/handle/344007/42523]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Xiang; Li, Shikun |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Henan Univ Sci & Technol, Coll Chem & Chem Engn, Luoyang 471023, Peoples R China 3.Henan Univ Sci & Technol, Coll Mat Sci & Engn, Luoyang 471023, Peoples R China 4.Xinjiang Univ, Sch Chem Engn & Technol, State Key Lab Chem & Utilizat Carbon Based Energy, Urumqi 830046, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Junhui,Li, Mengting,Zhang, Wenke,et al. Controllable preparation of Co-based catalysts doped with Cu and Mo for boosting hydrogen evolution[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2024,1003:9. |
| APA | Liu, Junhui.,Li, Mengting.,Zhang, Wenke.,Li, Xiang.,Zhao, Yuan.,...&Li, Shikun.(2024).Controllable preparation of Co-based catalysts doped with Cu and Mo for boosting hydrogen evolution.JOURNAL OF ALLOYS AND COMPOUNDS,1003,9. |
| MLA | Liu, Junhui,et al."Controllable preparation of Co-based catalysts doped with Cu and Mo for boosting hydrogen evolution".JOURNAL OF ALLOYS AND COMPOUNDS 1003(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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