Switchable reductive amination of aldehydes over metal-encapsulated S-1 zeolites with tunable acid-base properties
文献类型：期刊论文
| 作者 | Lu, Qiqi2,4; Sun, Jiangmin2,5; Wei, Xiu-Zhi6; Zhang, Qi3; Zhang, Xinghua3; Chen, Lungang3; Liu, Jianguo3; Chen, Yubao1; Ma, Longlong3 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2024-05-25 |
| 卷号 | 678页码:9 |
| 关键词 | Reductive amination Aldehydes Amines Imines Acid-base properties Selectivity control |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2024.119653 |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) ; Chen, Yubao(chenyubao@ynnu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Catalytic reductive amination of aldehydes is a valuable strategy to synthesize nitrogen-containing compounds but often suffers from low selectivity and complex reaction mechanisms. This study aims to develop a selective control method for the syntheses of primary amines and secondary imines, which are widely used in fine and bulk chemicals, materials, and pharmaceuticals. Metal-encapsulated zeolite is a special type of catalyst that combines the advantages of metal nanoparticles and zeolites, such as high activity and selectivity. Herein, metal- encapsulated zeolites (Pd-M@S-1, M=Ni, =Ni, Mn, Co) were applied as catalysts for the reductive amination of aromatic aldehydes. Results showed that the reductive amination of aldehydes over Pd-M@S-1 catalysts can be selectively switched between primary amines over Pd0.6@S-1 and secondary imines over Pd0.6Ni@S-1 by tuning the acid-base properties of the catalysts. The effect of acid-base properties of catalysts on selectivity control was claimed by conducting control experiments, time-dependent curves, and detailed characterizations. |
| WOS关键词 | MOLECULAR-HYDROGEN ; NI ; NANOPARTICLES ; AMINES |
| 资助项目 | National Key R & D Pro-gram of China[2022YFE0207200] ; National Natural Science Founda-tion of China[51976225] ; National Natural Science Founda-tion of China[52236010] ; Fundamental Research Funds for the Central Universities[2242022R10058] ; Key Project of Yunnan Fundamental Research Program[202301AS070011] ; Academician and Expert Workstation of Yunnan Province, China[202205AF150024] |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001290861000001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Key R & D Pro-gram of China ; National Natural Science Founda-tion of China ; Fundamental Research Funds for the Central Universities ; Key Project of Yunnan Fundamental Research Program ; Academician and Expert Workstation of Yunnan Province, China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/42599]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo; Chen, Yubao; Ma, Longlong |
| 作者单位 | 1.Yunnan Normal Univ, Sch Energy & Environm Sci, Kunming 650500, Yunnan, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Sci & Technol China, Dept Engn Sci, Hefei 230026, Peoples R China 6.He Fei Gotion High Tech Power Energy Co Ltd, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Qiqi,Sun, Jiangmin,Wei, Xiu-Zhi,et al. Switchable reductive amination of aldehydes over metal-encapsulated S-1 zeolites with tunable acid-base properties[J]. APPLIED CATALYSIS A-GENERAL,2024,678:9. |
| APA | Lu, Qiqi.,Sun, Jiangmin.,Wei, Xiu-Zhi.,Zhang, Qi.,Zhang, Xinghua.,...&Ma, Longlong.(2024).Switchable reductive amination of aldehydes over metal-encapsulated S-1 zeolites with tunable acid-base properties.APPLIED CATALYSIS A-GENERAL,678,9. |
| MLA | Lu, Qiqi,et al."Switchable reductive amination of aldehydes over metal-encapsulated S-1 zeolites with tunable acid-base properties".APPLIED CATALYSIS A-GENERAL 678(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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