Ozonolysis with MnO2: A Safe and Cost-Efficient Way for Producing Aldehydes and Ketones
文献类型：期刊论文
| 作者 | Ren, Tianyu1; Luo, Yang1; Chen, Xiaoli2; Wang, Chenguang1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2024-08-15 |
| 卷号 | 12期号:34页码:12719-12725 |
| 关键词 | ozonolysis biomass valorization aldehydes MnO2 sustainable kinetics |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.4c05462 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | Ozonolysis is a highly promising reaction for biomass valorization due to high efficiency, value-added carbonyl products, cheap oxidant, and mild conditions. However, the generation and accumulation of explosive peroxides during ozonolysis can be a risk and obstacle for large application. Herein, we propose a simple method that treats ozonolysis products with MnO2 to decompose and reduce the complex peroxides. Here, 60-90% peroxides can be removed within minutes at ambient conditions. Solvent and substrate structures influence MnO2 activity. We further propose a novel in situ MnO2-assisted ozonolysis, which restrains formation of peroxides while promotes aldehydes formation. Kinetic investigations indicated that H2O2 decomposition at low concentration is a first-order reaction, while it accelerated at high concentration due to an involvement of second-order decomposition of an organic peroxide generated in a rapid equilibrium with H2O2 and aldehyde. This work suggests that ozonolysis enables greener biomass valorization with more sustainable carbonyl products. |
| WOS关键词 | HYDROGEN-PEROXIDE ; REDUCTIVE OZONOLYSIS ; TANDEM OZONOLYSIS ; DIRECT CONVERSION ; ONE-POT ; FRAGMENTATION ; DECOMPOSITION ; ALKENES ; EUGENOL ; TRANSFORMATIONS |
| 资助项目 | China Postdoctoral Science Foundation[2023M743509] ; Guangdong Basic and Applied Basic Research Foundation[2024A1515010569] ; Guangzhou Municipal Science and Technology Bureau[2024A04J4679] ; National Natural Science Foundation of China[52276220] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001292273300001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | China Postdoctoral Science Foundation ; Guangdong Basic and Applied Basic Research Foundation ; Guangzhou Municipal Science and Technology Bureau ; National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/42638]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Anal & Test Ctr, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Tianyu,Luo, Yang,Chen, Xiaoli,et al. Ozonolysis with MnO2: A Safe and Cost-Efficient Way for Producing Aldehydes and Ketones[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2024,12(34):12719-12725. |
| APA | Ren, Tianyu,Luo, Yang,Chen, Xiaoli,&Wang, Chenguang.(2024).Ozonolysis with MnO2: A Safe and Cost-Efficient Way for Producing Aldehydes and Ketones.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,12(34),12719-12725. |
| MLA | Ren, Tianyu,et al."Ozonolysis with MnO2: A Safe and Cost-Efficient Way for Producing Aldehydes and Ketones".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 12.34(2024):12719-12725. |
入库方式： OAI收割
来源：广州能源研究所
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