Biomass-tar-derived oxygen-enriched porous carbon as a high-performance carbon electrode material for double electric layer and zinc-ion hybrid supercapacitor
文献类型：期刊论文
| 作者 | Ni, Xuanyuan2,3,4,5,6; Zhao, Yunxing2,3,4,6; Cai, Pengcheng2,3,4,5,6; Xu, Qing1,5; Li, Denian2,3,4,6 |
| 刊名 | DIAMOND AND RELATED MATERIALS
 |
| 出版日期 | 2024-10-01 |
| 卷号 | 148页码:10 |
| 关键词 | Biomass tar Porous carbon Supercapacitors Template modulation |
| ISSN号 | 0925-9635 |
| DOI | 10.1016/j.diamond.2024.111451 |
| 通讯作者 | Xu, Qing(xuqing-zj@163.com) ; Li, Denian(lidn@ms.giec.ac.cn) |
| 英文摘要 | Carbon-based capacitor electrodes have the advantages of high capacitance value, superior recyclability, and inexpensive raw materials, which fuel the application of capacitors in large-scale energy storage. Biomass tar is a hazardous waste that can be recycled as a low-cost carbon electrode precursor for capacitors, due to its retaining biomass-based heteroatom. In this study, hierarchically porous carbon with cross-linked structure was fabricated by using a nano-Al2O3 template combined with the KOH activation technique, in which the gamma-Al2O3 has a size of only 10 nm with high specific surface area, thus optimizing the pore structure of the carbon material. The resulting optimal material, BTC-0.2-2-800, contains abundant pore structure and extremely high oxygen content, delivers low resistance and excellent rate performance with high specific capacitance of 292.1 F g- 1 and 221.7 F g- 1 at 1 A g- 1 and 20 A g- 1, respectively, in double electric layer supercapacitors (EDLCs). Besides, no significant capacity degradation after 10,000 charging and discharging cycles at 10 A g- 1 was found. The two-electrode device prepared using Na2SO4 electrolyte achieves a high energy density of 43.18 Wh kg- 1 at the power density of 1000 W kg- 1, which can light up a 2 V LED lamp. Moreover, Zinc-ion hybrid supercapacitor (ZIHSC) fabricated with BTC-0.2-2-800 carbon electrode accounts for the energy densities of 69.82 Wh kg- 1 and 49.39 Wh kg- 1 at the power densities of 40 W kg- 1 and 400 W kg- 1, respectively. This study reveals the great potential of biomass-tar-derived carbon as a high-performance electrode material, which may provide an opportunities for the resource utilization of hazardous wastes. |
| WOS关键词 | NITROGEN |
| 资助项目 | Guangdong Basic and Applied Basic Research Foundation[2022A1515011653] ; Youth Inno-vation Promotion Association CAS[2021349] ; Guangdong youth talent support program[2021TQ06L121] |
| WOS研究方向 | Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001295169100001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Guangdong Basic and Applied Basic Research Foundation ; Youth Inno-vation Promotion Association CAS ; Guangdong youth talent support program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/42641]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Xu, Qing; Li, Denian |
| 作者单位 | 1.Guangdong Prov Key Lab Intelligent Equipment South, Guangzhou, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.Guangdong Ocean Univ, Coll Ocean Engn & Energy, 1,Haida Rd, Zhanjiang 524088, Peoples R China 6.Guangdong Prov Key Lab High Qual Recycling End of, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ni, Xuanyuan,Zhao, Yunxing,Cai, Pengcheng,et al. Biomass-tar-derived oxygen-enriched porous carbon as a high-performance carbon electrode material for double electric layer and zinc-ion hybrid supercapacitor[J]. DIAMOND AND RELATED MATERIALS,2024,148:10. |
| APA | Ni, Xuanyuan,Zhao, Yunxing,Cai, Pengcheng,Xu, Qing,&Li, Denian.(2024).Biomass-tar-derived oxygen-enriched porous carbon as a high-performance carbon electrode material for double electric layer and zinc-ion hybrid supercapacitor.DIAMOND AND RELATED MATERIALS,148,10. |
| MLA | Ni, Xuanyuan,et al."Biomass-tar-derived oxygen-enriched porous carbon as a high-performance carbon electrode material for double electric layer and zinc-ion hybrid supercapacitor".DIAMOND AND RELATED MATERIALS 148(2024):10. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。