Highly dispersed and stable Schiff base nickel catalyst on multi-walled carbon nanotubes promote ethylene oligomerization
文献类型：期刊论文
| 作者 | Li, Yang2; He, Chao3; Song, Da1; Fan, Mingyang4; Guo, Lijun2; Zhai, Xue2; Li, Feng2; Li, Cuiqin2; Huang, Zhen1 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2024-10-01 |
| 卷号 | 497页码:9 |
| 关键词 | alpha-Olefin Ethylene oligomerization Multi-walled carbon nanotubes Schiff base nickel catalyst |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2024.154447 |
| 通讯作者 | Li, Cuiqin(dqpilicuiqin@126.com) ; Huang, Zhen(huangzhen@ms.giec.ac.cn) |
| 英文摘要 | alpha-Olefins are essential chemical raw materials in the synthesis of emulsifiers, plasticizers, and other value-added chemicals, and ethylene oligomerization is the main method used for preparing alpha-olefins. However, catalysts employed in ethylene oligomerization have drawbacks such as poor selection of target products, catalyst particle aggregation, and deactivation. To prevent the aggregation of the catalyst and expose a large number of active sites, we propose an anchoring strategy to stabilize and uniformly disperse catalysts on multi-walled carbon nanotubes (MWCNTs). Hybrid catalysts (SCn@MWCNTs) fabricated using the strategy exhibited considerably higher catalytic performance compared with homogeneous Schiff base nickel catalysts (SCn) owing to the combined effects of MWCNTs and active nickel centers. Under optimal catalytic conditions (temperature: 25 degrees C; Al/Ni molar ratio: 500 (SCn); Al/Ni molar ratio: 700 (SCn@MWCNTs); pressure: 0.7 MPa), the activities of SC1 and SC1@MWCNTs were 6.56 x 104 and 8.25 x 104 g/(mol Ni & sdot;h), respectively. In particular, SC1@MWCNTs showed remarkable recyclability and catalytic stability. |
| WOS关键词 | POLYMERIZATION ; COMPLEXES ; BINDING ; DIMERIZATION ; OXIDATION ; GRAPHENE ; LIGANDS ; XPS |
| 资助项目 | National Natural Science Foundation of China[52076209] ; Foundation and Applied Foundation Research of Guangdong Province[2022B1515020045] ; Heilongjiang Key Research Project of China[JD22A026] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001295238900001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; Foundation and Applied Foundation Research of Guangdong Province ; Heilongjiang Key Research Project of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/42644]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Cuiqin; Huang, Zhen |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Northeast Petr Univ, Coll Chem & Chem Engn, Prov Key Lab Polyolefin New Mat, Daqing 163318, Peoples R China 3.PetroChina Lanzhou Petrochem Yulin Chem Co Ltd, Yulin 719000, Peoples R China 4.South China Univ Technol, Coll Elect Power, Guangzhou 510641, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yang,He, Chao,Song, Da,et al. Highly dispersed and stable Schiff base nickel catalyst on multi-walled carbon nanotubes promote ethylene oligomerization[J]. CHEMICAL ENGINEERING JOURNAL,2024,497:9. |
| APA | Li, Yang.,He, Chao.,Song, Da.,Fan, Mingyang.,Guo, Lijun.,...&Huang, Zhen.(2024).Highly dispersed and stable Schiff base nickel catalyst on multi-walled carbon nanotubes promote ethylene oligomerization.CHEMICAL ENGINEERING JOURNAL,497,9. |
| MLA | Li, Yang,et al."Highly dispersed and stable Schiff base nickel catalyst on multi-walled carbon nanotubes promote ethylene oligomerization".CHEMICAL ENGINEERING JOURNAL 497(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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