Carbon Nanofiber-Encapsulated FeCoNiCuMn Sulfides with Tunable S Doping for Enhanced Oxygen Evolution Reaction
文献类型：期刊论文
| 作者 | Sun, Yuhan1; Shen, Chen2; Wang, Mingran1; Cao, Yang1; Wang, Qianwei1; Rong, Jiayi1; He, Tong3; Li, Duanyang4; Cao, Feng1 |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2024-09-01 |
| 卷号 | 14期号:9页码:10 |
| 关键词 | high-entropy transition metal sulfides oxygen evolution reaction electrospinning carbon nanofibers |
| DOI | 10.3390/catal14090626 |
| 通讯作者 | He, Tong(tonghe503@126.com) ; Li, Duanyang(dyli@alum.imr.ac.cn) ; Cao, Feng(caof@atm.neu.edu.cn) |
| 英文摘要 | The oxygen evolution reaction (OER) stands out as a key electrochemical process for the conversion of clean energy. However, the practical implementation of OER is frequently impeded by its slow kinetics and the necessity for scarce and expensive noble metal catalysts. High-entropy transition metal sulfides (HETMS) stand at the forefront of OER catalysts, renowned for their exceptional catalytic performance and diversity. Herein, we have synthesized a HETMS catalyst, (FeCoNiCuMn50)S2, encapsulated within carbon nanofibers through a one-step process involving the synergistic application of electrospinning and chemical vapor deposition. By precisely controlling the doping levels of sulfur, we have demonstrated that sulfur incorporation significantly increases the exposed surface area of alloy particles on carbon nanofibers and optimizes the electronic configuration of the alloy elements. These findings reveal that sulfur doping is instrumental in the substantial improvement of the catalyst's OER performance. Notably, the catalyst showed optimal activity at a sulfur-to-metal atom ratio of 2:1, delivering an overpotential of 254 mV at a current density of 10 mA cm-2 in 1.0 M KOH solution. Furthermore, the (FeCoNiCuMn50)S2 catalyst exhibited remarkable electrochemical stability, underscoring its potential as an efficient and robust OER electrocatalyst for sustainable energy applications. |
| WOS关键词 | NANOPARTICLES ; EFFICIENT |
| 资助项目 | National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province of China[2023-MS-070] ; Natural Science Foundation of Liaoning Province of China[2022-MS-293] ; [51971059] ; [52371150] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001323679300001 |
| 出版者 | MDPI |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/43005]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | He, Tong; Li, Duanyang; Cao, Feng |
| 作者单位 | 1.Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat MoE, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Northeastern Univ, Analyt & Testing Ctr, Shenyang 110819, Peoples R China 4.Shenyang Univ, Coll Mech Engn, Shenyang 110003, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yuhan,Shen, Chen,Wang, Mingran,et al. Carbon Nanofiber-Encapsulated FeCoNiCuMn Sulfides with Tunable S Doping for Enhanced Oxygen Evolution Reaction[J]. CATALYSTS,2024,14(9):10. |
| APA | Sun, Yuhan.,Shen, Chen.,Wang, Mingran.,Cao, Yang.,Wang, Qianwei.,...&Cao, Feng.(2024).Carbon Nanofiber-Encapsulated FeCoNiCuMn Sulfides with Tunable S Doping for Enhanced Oxygen Evolution Reaction.CATALYSTS,14(9),10. |
| MLA | Sun, Yuhan,et al."Carbon Nanofiber-Encapsulated FeCoNiCuMn Sulfides with Tunable S Doping for Enhanced Oxygen Evolution Reaction".CATALYSTS 14.9(2024):10. |
入库方式： OAI收割
来源：广州能源研究所
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