Recent progress in thermal catalytic conversion of CO2: Insights into synergies with alkane or biomass transformations
文献类型：期刊论文
| 作者 | Lei, Guozhi1,2,3; Wang, Zhihao1,2,3; Xia, Shengpeng1,2,3; Fan, Yuyang4,5; Zhao, Kun1,2,3; Zhao, Zengli1,2,3; Zheng, Anqing1,2,3 |
| 刊名 | FUEL
 |
| 出版日期 | 2025-02-01 |
| 卷号 | 381页码:20 |
| 关键词 | Alkane dehydrogenation Biomass conversion Coupling transformation Thermal catalysis CO2 conversion |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2024.133366 |
| 通讯作者 | Zhao, Kun(zhaokun@ms.giec.ac.cn) ; Zheng, Anqing(zhengaq@ms.giec.ac.cn) |
| 英文摘要 | To achieve the goals of carbon peaking and carbon neutrality, thermal catalytic reactions that convert CO2 2 into various commodity chemicals offer promising solutions. This review summarizes four prevalent types of CO2 2 thermal catalysts tailored for producing CO, alcohols, hydrocarbons, and cyclic carbonates. A comprehensive examination is provided on the mechanisms of these catalysts, including the redox mechanism and the formate mechanism for CO2 2 to CO, the CO intermediate pathway and the formate pathway from CO2 2 to methanol, as well as the Fischer-Tropsch synthesis (FTs) route and the methanol-mediated route from CO2 2 to hydrocarbons. Key emphasis is placed on the mechanism-guided design of these catalysts and the identification and engineering of their active sites to improve catalytic performance. Furthermore, recognizing the substantial requirement of H2 2 in the thermal catalytic conversion of CO2, 2 , we examine the feasibility of the co-conversion of CO2 2 and alkanes/ biomass for overcoming the thermodynamic equilibrium limit of individual conversion and elucidate the synergistic mechanisms and catalyst development strategies for the coupling reactions. Building on this knowledge, the future direction of the co-conversion of CO2 2 and alkanes/biomass is evaluated, including the rational design of novel bifunctional catalysts via the selection of active metal/metal oxides, the introduction of doping and defects, and the engineering of supports, compositions, and morphologies. This review aims to lay the foundation for an in-depth investigation into the co-conversion of CO2 2 and alkanes/biomass. |
| WOS关键词 | METAL-ORGANIC FRAMEWORK ; GAS-SHIFT REACTION ; HIGHLY SELECTIVE CONVERSION ; CARBON-DIOXIDE ; OXIDATIVE DEHYDROGENATION ; METHANOL SYNTHESIS ; LIGHT OLEFINS ; ACTIVE-SITES ; HETEROGENEOUS CATALYSTS ; PROPANE DEHYDROGENATION |
| 资助项目 | National Natural Science Foundation of China[52276221] ; National Natural Science Foundation of China[22279144] ; Guangdong Natural Science Funds for Distinguished Young Scholars[2023B1515020093] ; Guangdong Natural Science Funds for Distinguished Young Scholars[2023B1515020048] ; Key Research and Development Program of Guangzhou[202206010122] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001335133100001 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Natural Science Funds for Distinguished Young Scholars ; Key Research and Development Program of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/43257]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhao, Kun; Zheng, Anqing |
| 作者单位 | 1.Univ Sci & Technol China, Sch Energy Sci & Engn, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & Dev, Guangzhou 510640, Peoples R China 4.Tech Univ Munich, Dept Chem, D-85747 Garching, Germany 5.Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany |
| 推荐引用方式 GB/T 7714 | Lei, Guozhi,Wang, Zhihao,Xia, Shengpeng,et al. Recent progress in thermal catalytic conversion of CO2: Insights into synergies with alkane or biomass transformations[J]. FUEL,2025,381:20. |
| APA | Lei, Guozhi.,Wang, Zhihao.,Xia, Shengpeng.,Fan, Yuyang.,Zhao, Kun.,...&Zheng, Anqing.(2025).Recent progress in thermal catalytic conversion of CO2: Insights into synergies with alkane or biomass transformations.FUEL,381,20. |
| MLA | Lei, Guozhi,et al."Recent progress in thermal catalytic conversion of CO2: Insights into synergies with alkane or biomass transformations".FUEL 381(2025):20. |
入库方式： OAI收割
来源：广州能源研究所
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