中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An investigation on synergistic effects and kinetic characteristics of pyrolysis of kitchen waste components: Starch, protein and lipid

文献类型:期刊论文

作者Yao, Liming1,2,3; Wu, Benteng2,3; Fan, Honggang2,3; Gu, Jing2,3; Yuan, Haoran2,3; Xie, Jun1,2,3
刊名JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
出版日期2024-12-01
卷号12期号:6页码:10
关键词Pyrolysis Kitchen waste Synergistic effect Kinetics
ISSN号2213-2929
DOI10.1016/j.jece.2024.114619
通讯作者Yuan, Haoran(yuanhr@ms.giec.ac.cn)
英文摘要The large volume and complex composition of kitchen waste necessitate environmentally sound treatment methods. Pyrolysis emerges as a promising way in treatment and utilization of kitchen waste. However, due to the complex composition and structure of kitchen waste, its pyrolysis characteristics remain unclear. Herein, thermogravimetric analysis was used to compare the pyrolysis characteristics of starch, protein, and lipid in kitchen waste as well as their synergistic interactions at various heating rates. Activation energy and reaction mechanisms were explored using the model-free and model methods. Evolved vapors were analyzed with thermogravimetric-mass spectrometry. The results showed that the presence of lipid slowed down the escape of volatile fractions when co-pyrolyzing with starch, protein or their mixtures (250-420 degrees C), but promoted the overall conversion with lower solid residual rates (Delta W > 1.6 wt%) and higher generation of gaseous products (mainly C2H4/CO and H2O). The increased activation energies led by lipid addition during co-pyrolysis were mainly because of the liquid phase formation over starch and protein, thereby preventing the deep degradation of organics. Contrary to the pyrolysis of starch, protein and lipid, distinct reaction mechanisms were revealed during the co-pyrolysis, with starch/lipid, starch/protein, protein/lipid and starch/protein/lipid following reaction models of F1.5, R1, ZH and F2, respectively. This study provides theoretical support for the development of advanced pyrolysis-based technologies for kitchen waste treatment.
WOS关键词CO-PYROLYSIS ; TG-FTIR ; CARBOHYDRATE ; MICROALGAE ; CELLULOSE ; INSIGHT ; OIL
资助项目National Key R & D Program of China[2022YFC3902403] ; National Natural Science Foundation of China[52325606] ; Guangdong Basic and Applied Basic Research Foun-dation[2021B1515020068]
WOS研究方向Engineering
语种英语
WOS记录号WOS:001351999200001
出版者ELSEVIER SCI LTD
资助机构National Key R & D Program of China ; National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foun-dation
源URL[http://ir.giec.ac.cn/handle/344007/43455]  
专题中国科学院广州能源研究所
通讯作者Yuan, Haoran
作者单位1.South China Agr Univ, Inst Biomass Engn, Guangzhou 510642, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714
Yao, Liming,Wu, Benteng,Fan, Honggang,et al. An investigation on synergistic effects and kinetic characteristics of pyrolysis of kitchen waste components: Starch, protein and lipid[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2024,12(6):10.
APA Yao, Liming,Wu, Benteng,Fan, Honggang,Gu, Jing,Yuan, Haoran,&Xie, Jun.(2024).An investigation on synergistic effects and kinetic characteristics of pyrolysis of kitchen waste components: Starch, protein and lipid.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,12(6),10.
MLA Yao, Liming,et al."An investigation on synergistic effects and kinetic characteristics of pyrolysis of kitchen waste components: Starch, protein and lipid".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 12.6(2024):10.

入库方式: OAI收割

来源:广州能源研究所

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