Waste lithium-ion batteries for selective transfer hydrogenation of bio-based ethyl levulinate: Experiments, kinetics and economic assessment
文献类型：期刊论文
| 作者 | Zhang, Jun1,2,3,4; Li, Zihao1,5; Liu, Huiyu1,2,3,4; Shan, Rui1,2,3,4; Yuan, Haoran1,2,3,4; Chen, Yong1,2,3,4 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2024-12-01 |
| 卷号 | 501页码:8 |
| 关键词 | Waste lithium-ion batteries Transfer hydrogenation Ethyl levulinate gamma-Valerolactone Economic assessment |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2024.157570 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | The present research firstly developed the waste lithium-ion batteries as heterogenous catalysts for catalytic upgrading of bio-based ethyl levulinate (EL) into gamma-valerolactone (GVL) using 2-propanol as both the hydrogen source and solvent. The existing acid and basic sites in waste lithium-ion batteries significantly favored the MPV reduction of bio-based EL, wherein 87.4 % GVL yield and low activation energy of 35.2 kJ/mol were achieved. Furthermore, the waste lithium-ion batteries contributed to H-transfer upgrading of a variety of building blocks containing unsaturated groups, such as aldehydes and esters. More gratifyingly, the economic assessment demonstrated that EL-to-GVL transformation via H-transfer manner was preferred as compared with the traditional hydrogenation, in which the total cost for converting 1 kg EL declined by 10.58 $ and overall profit increased by 12.35 $. In addition, the plausible mechanism for H-transfer upgrading of EL into GVL over waste lithium-ion batteries was proposed. |
| WOS关键词 | REDUCTION |
| 资助项目 | National Natural Science Foundation of China[52276219] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] ; CAS Project for Young Scientists in Basic Research[YSBR-044] ; Youth Innovation Promotion Association CAS[2023367] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001359987400001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; CAS Project for Young Scientists in Basic Research ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/43544]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Univ Sci & Technol China, Sch Energy Sci & Engn, Hefei 230022, Peoples R China 5.China Agr Univ, Coll Informat & Elect Engn, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jun,Li, Zihao,Liu, Huiyu,et al. Waste lithium-ion batteries for selective transfer hydrogenation of bio-based ethyl levulinate: Experiments, kinetics and economic assessment[J]. CHEMICAL ENGINEERING JOURNAL,2024,501:8. |
| APA | Zhang, Jun,Li, Zihao,Liu, Huiyu,Shan, Rui,Yuan, Haoran,&Chen, Yong.(2024).Waste lithium-ion batteries for selective transfer hydrogenation of bio-based ethyl levulinate: Experiments, kinetics and economic assessment.CHEMICAL ENGINEERING JOURNAL,501,8. |
| MLA | Zhang, Jun,et al."Waste lithium-ion batteries for selective transfer hydrogenation of bio-based ethyl levulinate: Experiments, kinetics and economic assessment".CHEMICAL ENGINEERING JOURNAL 501(2024):8. |
入库方式： OAI收割
来源：广州能源研究所
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