Tailoring selectivity in furfural hydrogenolysis over NiCoAl catalyst through a simple rinsing process
文献类型：期刊论文
| 作者 | Zhao, Zepeng2,3; Zhou, Wenguang2,3; Chang, Guozhang6; Chen, Lungang4; Wang, Chenguang2,3,5; Liao, Yuhe5; Long, Jinxing1; Ma, Longlong4; Liu, Yong2,3,7 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2024-12-01 |
| 卷号 | 440页码:11 |
| 关键词 | Furfural Structure-activity relationship Cyclopentanone Tetrahydrofuran alcohol NiCoAl |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2024.115845 |
| 通讯作者 | Liu, Yong(liuyongncu@ncu.edu.cn) |
| 英文摘要 | In this study, the structure-activity relationships were investigated in converting biomass-derived furfural into cyclopentanone (CPO) or tetrahydrofuran alcohol (THFA) using a rinsing method to modulate the NiCoAl catalyst. Characterization of two catalysts, NiCoAl (without rinsing) and NiCoAl-R (with rinsing), reveals differences in morphology, composition, and acidity. Rinsing induced a transition from agglomerate to layered structure in NiCoAl-R, which exhibited higher acid strength and improved Lewis to Br & Oslash;nsted acid ratio. NiCoAl-R contained a high percentage of metal oxides, while NiCoAl had a high percentage of metallic species on its surface. These distinctions resulted in varied performance in FFA hydrogenolysis, with NiCoAl-R favoring CPO formation and NiCoAl facilitating THFA production. In situ DRIFTS experiments reveals differing furfural sorption states, and DFT calculations highlighted the higher activity of metal oxides in ring-opening reactions. This investigation elucidates the intricate relationship between catalyst properties and performance, offering insights for tailored catalyst design in biomass conversion. |
| WOS关键词 | CYCLOPENTANONE ; HYDROGENATION ; CONVERSION ; BIOMASS ; REARRANGEMENT ; CHEMICALS ; EFFICIENT ; ALCOHOL |
| 资助项目 | National Natural Science Foundation of China[52066016] ; National Natural Science Foundation of China[52466017] ; National Natural Science Foundation of China[22178129] ; Natural Science Foundation of Jiangxi Province[20242BAB25277] ; Open Foundation of Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education[etcc202402] ; Talent Program of Jiangxi Province of China[jxsq2020102023] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001360553100001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Jiangxi Province ; Open Foundation of Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education ; Talent Program of Jiangxi Province of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/43593]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Yong |
| 作者单位 | 1.South China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China 2.Nanchang Univ, Sch Resources & Environm, Nanchang 330047, Peoples R China 3.Nanchang Univ, Engn Res Ctr Watershed Carbon Neutral, Minist Educ, Nanchang 330047, Peoples R China 4.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 6.Shandong Univ Sci & Technol, Inst Yellow River Delta Earth Surface Proc & Ecol, Coll Energy Storage Technol, Qingdao 266590, Peoples R China 7.Southeast Univ, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Zepeng,Zhou, Wenguang,Chang, Guozhang,et al. Tailoring selectivity in furfural hydrogenolysis over NiCoAl catalyst through a simple rinsing process[J]. JOURNAL OF CATALYSIS,2024,440:11. |
| APA | Zhao, Zepeng.,Zhou, Wenguang.,Chang, Guozhang.,Chen, Lungang.,Wang, Chenguang.,...&Liu, Yong.(2024).Tailoring selectivity in furfural hydrogenolysis over NiCoAl catalyst through a simple rinsing process.JOURNAL OF CATALYSIS,440,11. |
| MLA | Zhao, Zepeng,et al."Tailoring selectivity in furfural hydrogenolysis over NiCoAl catalyst through a simple rinsing process".JOURNAL OF CATALYSIS 440(2024):11. |
入库方式： OAI收割
来源：广州能源研究所
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