Co-Feeding CO2 for Methylfuran Aromatization over Bifunctional Zeolite-Supported ZnMoO4
文献类型：期刊论文
| 作者 | Xia, Shengpeng2,3; Zhao, Kun2,3; Gao, Yunfei4; Fan, Yuyang5,6; Wang, Chenyang7; Yu, Tongpo8; Wang, Hong8; Zhang, Jinyang8; Wang, Zhandong8; Zhu, Xing1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2024-11-21 |
| 页码 | 12 |
| 关键词 | CO2 conversion 2-Methylfuran CO2 co-feeding Zeolite Reaction mechanism |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202420779 |
| 通讯作者 | Wang, Zhandong(zhdwang@ustc.edu.cn) ; Zheng, Anqing(zhengaq@ms.giec.ac.cn) |
| 英文摘要 | Aromatization of biofuran offers promising approaches for sustainable biochemical production. However, this process is often hampered by low yields and severe coking on traditional zeolite catalysts. Herein, we report co-feeding CO2 for 2-methylfuran (MF) aromatization (CCMA) over bifunctional ZSM-5 supported ZnMoO4. This bifunctional catalyst can achieve both MF and CO2 conversions of >97 %, generating >85 % carbon yield of target arenes and CO with negligible alkenes (0.05 %). Meanwhile, coke formation is remarkably suppressed from 22.3 % to 8.6 %. ZnMoO4/ZSM-5 is capable of selectively manipulating the reaction intermediates and pathways of the CCMA reactions, favoring the cyclopentenones- and alkenes-based dehydro-aromatization rather than the benzofurans-based pathway. This finding challenges the prevailing understanding that MF aromatization follows a hydrocarbon pool mechanism. Moreover, the abundant surface oxygen vacancies of ZnMoO4 facilitate the adsorption of CO2 and its subsequent reaction with coke. These insights into reaction mechanism and catalyst design for co-conversion of CO2 and biofuran can offer guidelines for process intensification in biomass utilization with a carbon-negative manner. |
| WOS关键词 | PHOTOIONIZATION CROSS-SECTIONS ; OXIDATIVE DEHYDROGENATION ; MECHANISM ; AROMATICS ; METHANOL ; ISOMERS ; FURAN |
| 资助项目 | National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation[2023B1515020093] ; Guangdong Basic and Applied Basic Research Foundation[2023B1515020048] ; National Key Research and Development Program of China[2022YFA1504701] ; National Key Research and Development Program of China[2022YFB4101900] ; [52276221] ; [22279144] ; [22208104] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001361578000001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; National Key Research and Development Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/43634]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Zhandong; Zheng, Anqing |
| 作者单位 | 1.Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China 2.Univ Sci & Technol China, Chinese Acad Sci, Guangzhou Inst Energy Convers, Sch Energy Sci & Engn,Guangdong Prov Key Lab Renew, Guangzhou 510640, Peoples R China 3.Univ Sci & Technol China, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.East China Univ Sci & Technol, Inst Clean Coal Technol, Shanghai 200237, Peoples R China 5.Tech Univ Munich, Dept Chem, D-85747 Garching, Germany 6.Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany 7.Chinese Acad Sci, China Spallat Neutron Source, Inst High Energy Phys, Dongguan 523803, Peoples R China 8.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Shengpeng,Zhao, Kun,Gao, Yunfei,et al. Co-Feeding CO2 for Methylfuran Aromatization over Bifunctional Zeolite-Supported ZnMoO4[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024:12. |
| APA | Xia, Shengpeng.,Zhao, Kun.,Gao, Yunfei.,Fan, Yuyang.,Wang, Chenyang.,...&Zheng, Anqing.(2024).Co-Feeding CO2 for Methylfuran Aromatization over Bifunctional Zeolite-Supported ZnMoO4.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,12. |
| MLA | Xia, Shengpeng,et al."Co-Feeding CO2 for Methylfuran Aromatization over Bifunctional Zeolite-Supported ZnMoO4".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024):12. |
入库方式： OAI收割
来源：广州能源研究所
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