Pressure-induced phase transition and metallization in zirconium disulfide under different hydrostatic environments up to 25.3 GPa
文献类型:期刊论文
| 作者 | Xinyu Zhang; Lidong Dai; Haiying Hu; Meiling Hong; Chuang Li |
| 刊名 | Materials Research Bulletin
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| 出版日期 | 2024 |
| 卷号 | 175页码:112787 |
| 关键词 | Zrs2 Raman Spectroscopy Electrical Conductivity Metallic Phase Transition High Pressure |
| DOI | 10.1016/j.materresbull.2024.112787 |
| 英文摘要 | The pressurized behaviours of structure, vibration and electrical transport in zirconium disulfide have been systematically investigated in a diamond anvil cell (DAC) under different hydrostatic environments up to 25.3 GPa utilizing in-situ Raman spectroscopy, electrical conductivity measurement, high-resolution transmission electron microscopy (HRTEM) and first-principles theoretical calculations. Upon compression, our experimental results showed that ZrS2 underwent a phase transition accompanied by a semiconductor-to-metal transformation at 15.4 GPa under non-hydrostatic condition. Under hydrostatic condition, the corresponding phase transition occurred at a higher pressure of 17.5 GPa, indicating that the high-pressure phase transition is sensitive to the hydrostaticity in the sample chamber of DAC. Upon decompression, some absolutely new Raman peaks emerged at the pressures below 4.8 GPa and 2.9 GPa under non-hydrostatic and hydrostatic environments, respectively, which revealed an irreversible phase transition in ZrS2. Furthermore, our observations from selected-area electron diffraction patterns confirmed the irreversibility of the high-pressure phase transformation.
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| URL标识 | 查看原文 |
| 语种 | 英语 |
| 源URL | ![]() |
| 专题 | 地球化学研究所_地球内部物质高温高压实验室 |
| 作者单位 | 1.Key Laboratory of High-temperature and High-pressure Study of the Earth's Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550081, China 2.University of Chinese Academy of Sciences, Beijing 100049, China |
| 推荐引用方式 GB/T 7714 | Xinyu Zhang,Lidong Dai,Haiying Hu,et al. Pressure-induced phase transition and metallization in zirconium disulfide under different hydrostatic environments up to 25.3 GPa[J]. Materials Research Bulletin,2024,175:112787. |
| APA | Xinyu Zhang,Lidong Dai,Haiying Hu,Meiling Hong,&Chuang Li.(2024).Pressure-induced phase transition and metallization in zirconium disulfide under different hydrostatic environments up to 25.3 GPa.Materials Research Bulletin,175,112787. |
| MLA | Xinyu Zhang,et al."Pressure-induced phase transition and metallization in zirconium disulfide under different hydrostatic environments up to 25.3 GPa".Materials Research Bulletin 175(2024):112787. |
入库方式: OAI收割
来源:地球化学研究所
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