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Structural, optical and photocatalytic investigations of cauliflower like SnO2/CdS nanocomposite prepared by the sol-gel method

文献类型:期刊论文

作者S. Shabna; S. C. Jeyakumar; M. Robinson Joel; S. Sahaya Jude Dhas; Sivakumar Aswathappa; Raju Suresh Kumar; Abdulrahman I. Almansour; Arun Aravind; Lolly Maria Jose; C. S. Biju
刊名Journal of Sol-Gel Science and Technology
出版日期2024
卷号115期号:3页码:1116-1134
关键词Metal Oxides nanocomposites Nanomaterial nanoparticles photocatalysis quantum Dots
DOI10.1007/s10971-024-06365-1
英文摘要

Crystal violet (CV), a cationic dye, has been established to be an extremely potent carcinogen, a mitotic toxin, and poisonous to mammalian cells. As a consequence, it is imperative to remove this specific dye before it is released into the environment because its presence inevitably has a devastating effect on humankind. The photocatalyst-mediated degradation of CV is a rapidly developing method of eliminating this hazardous dye from aqueous solutions, as demonstrated by the extensive reporting of its efficacy in recent times. In this study, we explore the photocatalytic activity of pure SnO2, CdS and SnO2/CdS nanocomposites which were fabricated by a facile sol-gel technique. Field emission scanning electron microscopic (FESEM) analysis revealed a cauliflower-like morphology for the SnO2/CdS nanocomposite. The optical band gaps of the nanoparticles were found to be 2.41, 2.04 and 2.28 eV for the SnO2, CdS, and SnO2/CdS, respectively. Moreover, the SnO2/CdS photocatalyst exhibits greater photocatalytic activity (73% degradation efficiency after 75 min) for the degradation of CV than that of the pure SnO2 and CdS nanomaterials. This enhanced performance is attributed to enhanced charge separation and reduced charge recombination rates in the SnO2/CdS photocatalyst activity, such that it could be used as a potential material to reduce water pollution in an economically viable way.

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专题地球化学研究所_地球内部物质高温高压实验室
作者单位1.Research Scholar, Register No: 20213082132004, Department of Physics and Research Centre, Malankara Catholic College, Mariagiri, 629153, Tamil Nadu, India
2.Affiliated to Manonmaniam Sundaranar University, Abishekapatti, 627012, Tirunelveli, TamilNadu, India
3.Department of Physics, Nesamony Memorial Christian College, Marthandam, 629165, Tamil Nadu, India
4.Department of Information Technology, Kings Engineering College, Sriperumbudur, 602117, Chennai, Tamil Nadu, India
5.Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, 602 105, Chennai, Tamil Nadu, India
6.Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou, 550081, China
7.Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
8.Centre for Advanced Functional Materials, Postgraduate and Research Department of Physics, Bishop Moore College, Mavelikara, Alappuzha, 690110, Kerala, India
9.Department of Physics, St. Alphonsa College of Arts and Science, Soosaipuram, Karinkal, 629157, Tamil Nadu, India
10.Formerly Assistant Professor, Department of Physics and Research Centre, Malankara Catholic College, Mariagiri, 629153, Tamil Nadu, India
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S. Shabna,S. C. Jeyakumar,M. Robinson Joel,et al. Structural, optical and photocatalytic investigations of cauliflower like SnO2/CdS nanocomposite prepared by the sol-gel method[J]. Journal of Sol-Gel Science and Technology,2024,115(3):1116-1134.
APA S. Shabna.,S. C. Jeyakumar.,M. Robinson Joel.,S. Sahaya Jude Dhas.,Sivakumar Aswathappa.,...&C. S. Biju.(2024).Structural, optical and photocatalytic investigations of cauliflower like SnO2/CdS nanocomposite prepared by the sol-gel method.Journal of Sol-Gel Science and Technology,115(3),1116-1134.
MLA S. Shabna,et al."Structural, optical and photocatalytic investigations of cauliflower like SnO2/CdS nanocomposite prepared by the sol-gel method".Journal of Sol-Gel Science and Technology 115.3(2024):1116-1134.

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来源:地球化学研究所

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