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Chinese Academy of Sciences Institutional Repositories Grid
Influence of crystallographic anisotropy on the electrical conductivity of apatite at high temperatures and high pressures

文献类型:期刊论文

作者Ziming Hu; Lidong Dai; Haiying Hu; Wenqing Sun; Mengqi Wang; Chenxin Jing; Chuanyu Yin; Song Luo; Jinhua Lai
刊名American Mineralogist
出版日期2024
卷号109期号:5页码:814-826
关键词Apatite, Electrical Conductivity, Anisotropy, Fluorine Conduction, High Pressure PhysicsAnd Chemistry Of Earth’s Deep Mantle And Core
DOI10.2138/am-2022-8900
英文摘要

The electrical conductivity of apatite single crystals along three main crystalline directions wasmeasured in situ using a YJ-3000t multi-anvil apparatus and a combined system consisting of theimpedance/gain-phase analyzer (Solartron 1260) and dielectric interface (Solartron 1296) at 973–1373 Kand 1.0–3.0 GPa. The obtained results indicate that the relationship between the electrical conductivityand temperature conforms to the Arrhenius relation. At 2.0 GPa, the electrical conductivity of apatitewith relatively high activation enthalpies of 1.92–2.24 eV shows a significant anisotropy with anextremely high anisotropic degree (τ = ~8–16) value. For a given [001] crystallographic orientation,the electrical conductivity of apatite slightly decreases with increasing pressure, and its correspondingactivation energy and activation volume of charge carriers are 2.05 ± 0.06 eV and 9.31 ± 0.98 cm3/mol,respectively. All of these observed anomalously high activation enthalpy and positive activation volume values suggest that the main conduction mechanism is related to the monovalent fluorine anion athigh temperature and high pressure. Furthermore, three representative petrological average schemes,including the parallel, Hashin-Shtrikman upper bound, and average models were selected to establishthe functional relation for the electrical conductivity of the phlogopite-apatite-peridotite rock systemalong with the volume percentages of apatite ranging from 1 to 10% at 973–1373 K and 2.0 GPa. Fora typical Hashin-Shtrikman upper bound model, the electrical conductivity-depth profile for peridotitecontaining the 10% volume percentage of apatite was successfully constructed in conjunction withour acquired anisotropic electrical conductivity results and available temperature gradient data (11.6and 27.6 K/km) at depths of 20–90 km. Although the presence of apatite in peridotite cannot explainthe high-conductivity anomalies in western Junggar of Xinjiang autonomous region, it may provide areasonable constraint on those of representative apatite-rich areas.

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专题地球化学研究所_地球内部物质高温高压实验室
作者单位1.Key Laboratory of High-Temperature and High-Pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences,Guiyang, 550081, China
2.University of Chinese Academy of Sciences, Beijing, 100049, China
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GB/T 7714
Ziming Hu,Lidong Dai,Haiying Hu,et al. Influence of crystallographic anisotropy on the electrical conductivity of apatite at high temperatures and high pressures[J]. American Mineralogist,2024,109(5):814-826.
APA Ziming Hu.,Lidong Dai.,Haiying Hu.,Wenqing Sun.,Mengqi Wang.,...&Jinhua Lai.(2024).Influence of crystallographic anisotropy on the electrical conductivity of apatite at high temperatures and high pressures.American Mineralogist,109(5),814-826.
MLA Ziming Hu,et al."Influence of crystallographic anisotropy on the electrical conductivity of apatite at high temperatures and high pressures".American Mineralogist 109.5(2024):814-826.

入库方式: OAI收割

来源:地球化学研究所

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