中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influence of Co Substitution on the Diamagnetic to Soft Ferromagnetic Switching in BaTiO3 Nanoparticles for Spintronic Applications

文献类型:期刊论文

作者V. Sherlin Vinita; S. C. Jeyakumar; C. John Clement Singh; S. Sahaya Jude Dhas; Soumya Rajan; C. S. Biju; Sivakumar Aswathappa; Raju Suresh Kumar; Abdulrahman I. Almansour
刊名Journal of Superconductivity and Novel Magnetism
出版日期2024
卷号37期号:5-7页码:999-1010
DOI10.1007/s10948-024-06750-5
英文摘要

We present our findings on the room temperature (RT) soft ferromagnetism (FM) of the sol-gel-prepared Co-doped barium titanate (BaTiO3) nanoparticles with two distinct Co concentrations (0.25 mol% and 0.5 mol%), that is appropriate for spintronic applications as evidenced by experimental observations. X-ray diffraction investigation revealed that the produced samples, which had diameters less than 100 nm, belonged to the pseudo-cubic phase of the BaTiO3 structure and did not exhibit any signs of the Co cluster or any other Co oxides. UV-visible absorption spectra demonstrate that the optical response is red shifted and the bandgap energy is lowered when Co is incorporated into the BaTiO3 lattice. The inclusion of cobalt ions may have brought about a change in size or an increase in surface defects, as evidenced by the PL spectra, which show that the intensity of emission peaks changes as the dopant concentration increases. In the 0.25 mol% Co-doped BaTiO3 sample, the FM behavior is clearly visible along with the paramagnetic (PM) phase at RT. Significantly, it becomes apparent that as the doping concentration is raised to 0.5 mol%, the saturation magnetization is reduced, and a pure phase of soft FM is obtained. This soft FM feature witnessed in 0.5 mol% doped BaTiO3 with low coercivity (96.8 Oe) and low saturation magnetization (9.7 × 10−3 emu/g) is likely due to oxygen vacancies and could set out as a promising magnetic material for possible spintronic applications.

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专题地球化学研究所_地球内部物质高温高压实验室
作者单位1.Department of Physics and Research Centre, Malankara Catholic College, Mariagiri, Kaliakkavilai, 629153, Tamil Nadu, India
2.Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli, 627012, Tamil Nadu, India
3.Department of Physics, Nesamony Memorial Christian College, Marthandam, 629165, Tamil Nadu, India
4.Department of Electronics and Communication Engineering, Kings Engineering College, Sriperumbudur, 602117, Chennai, Tamil Nadu, India
5.Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, 602 105, Tamil Nadu, India
6.Department of Basic Science and Humanities, Mangalam College of Engineering, Ettumanoor, 686631, Kerala, India
7.Department of Physics, Alphonsa College of Arts & Science, Karinkal, 629157, Tamil Nadu, India
8.Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, Guizhou, China
9.Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia
推荐引用方式
GB/T 7714
V. Sherlin Vinita,S. C. Jeyakumar,C. John Clement Singh,et al. Influence of Co Substitution on the Diamagnetic to Soft Ferromagnetic Switching in BaTiO3 Nanoparticles for Spintronic Applications[J]. Journal of Superconductivity and Novel Magnetism,2024,37(5-7):999-1010.
APA V. Sherlin Vinita.,S. C. Jeyakumar.,C. John Clement Singh.,S. Sahaya Jude Dhas.,Soumya Rajan.,...&Abdulrahman I. Almansour.(2024).Influence of Co Substitution on the Diamagnetic to Soft Ferromagnetic Switching in BaTiO3 Nanoparticles for Spintronic Applications.Journal of Superconductivity and Novel Magnetism,37(5-7),999-1010.
MLA V. Sherlin Vinita,et al."Influence of Co Substitution on the Diamagnetic to Soft Ferromagnetic Switching in BaTiO3 Nanoparticles for Spintronic Applications".Journal of Superconductivity and Novel Magnetism 37.5-7(2024):999-1010.

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来源:地球化学研究所

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