Highly robust and long-lasting superhydrophobic anti-corrosion coating: From laboratory development to real-world marine environment validation
文献类型：期刊论文
| 作者 | Zhang, Binbin1,2,3; Xue, Xiaochen2; Hou, Baorong2 |
| 刊名 | PROGRESS IN ORGANIC COATINGS
 |
| 出版日期 | 2025-12-01 |
| 卷号 | 209页码:13 |
| 关键词 | Superhydrophobic Anti-corrosion Robust Marine corrosion |
| ISSN号 | 0300-9440 |
| DOI | 10.1016/j.porgcoat.2025.109604 |
| 通讯作者 | Zhang, Binbin(zhangbinbin@qdio.ac.cn) |
| 英文摘要 | The construction of superhydrophobic materials as an effective anti-corrosion method has become a scientific consensus. However, two major challenges still hinder their transition from laboratory development to practical applications: insufficient interfacial mechanical stability and the inability of laboratory evaluation methods to accurately predict protective behavior and adaptability in real service environments. In this study, we designed a silica sand (SiO2) armored superhydrophobic composite coating, primarily composed of three layers: epoxy resin (EP) layer, large-scale SiO2 layer, and superhydrophobic 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane-modified titanium dioxide (F-TiO2) @ EP layer. Field-emission scanning electron microscope (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), contact/sliding angle measurements, sandpaper abrasion tests, electrochemical analysis, and neutral salt spray tests were used to evaluate the surface morphology, chemical composition, wettability, interfacial stability, and laboratory anti-corrosion performance. The results showed that the coating maintained a water contact angle (WCA) of 150.4 f 0.4 degrees and a sliding angle (SA) of 9.4 f 0.2 degrees even after 2000 sandpaper abrasion cycles (400 m abrasion distance), demonstrating exceptional mechanical stability. The low-frequency impedance modulus (|Z|0.01Hz) and charge transfer resistance (Rct) of the coating increased by five orders of magnitude, and the coating withstood 720 h of salt spray testing, confirming its superior anti-corrosion performance at the laboratory stage. More importantly, we evaluated the anti-corrosion performance of the prepared superhydrophobic coating in four corrosion zones of a real marine corrosion environment. The results revealed that the coating exhibited sustained anti-corrosion properties in the marine atmospheric zone and the splash zone. However, its long-term durability in the tidal zone and submerged zone was limited, indicating the need for further improvement and reinforcement. |
| WOS关键词 | CORROSION-RESISTANCE ; PERFORMANCE |
| 资助项目 | Shandong Provincial Natural Science Foundation[ZR2022YQ35] ; Taishan Scholars Program[tsqn202408278] |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001603148800001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/203731]  |
| 专题 | 中国科学院海洋研究所 |
| 通讯作者 | Zhang, Binbin |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, State Key Lab Adv Marine Mat, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, State Key Lab Adv Marine Mat, Qingdao, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Binbin,Xue, Xiaochen,Hou, Baorong. Highly robust and long-lasting superhydrophobic anti-corrosion coating: From laboratory development to real-world marine environment validation[J]. PROGRESS IN ORGANIC COATINGS,2025,209:13. |
| APA | Zhang, Binbin,Xue, Xiaochen,&Hou, Baorong.(2025).Highly robust and long-lasting superhydrophobic anti-corrosion coating: From laboratory development to real-world marine environment validation.PROGRESS IN ORGANIC COATINGS,209,13. |
| MLA | Zhang, Binbin,et al."Highly robust and long-lasting superhydrophobic anti-corrosion coating: From laboratory development to real-world marine environment validation".PROGRESS IN ORGANIC COATINGS 209(2025):13. |
入库方式： OAI收割
来源：海洋研究所
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