中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 海洋研究所
  3. 中国科学院海洋研究所
  4. 海洋腐蚀与防护研究发展中心
An environment-friendly efficient visible-light photocatalyst of P, Mo co-doped TiO2 nanoflowers hybridized with 2D porous g-C3N4 nanosheets for the antibacterial application

文献类型：期刊论文

作者Xue, Leilei2,3,5; Zhang, Jie3; Sun, Mengmeng3; Wang, Debao2; Zhang, Hui3,5; Zhang, Ruiyong3; Duan, Jizhou3; Sand, Wolfgang1,3,4; Hou, Baorong3
刊名JOURNAL OF ALLOYS AND COMPOUNDS
出版日期2025-11-05
卷号1044页码:15
关键词Synergistic antibacterial Photocatalytic antibacterial Visible light P, Mo co-doped TiO2
ISSN号0925-8388
DOI10.1016/j.jallcom.2025.182941
通讯作者Zhang, Jie(zhangjie@qdio.ac.cn) ; Sun, Mengmeng(sunmengmeng@qdio.ac.cn) ; Zhang, Ruiyong(ruiyong.zhang@qdio.ac.cn)
英文摘要Developing eco-friendly and efficient new antifouling materials is of vital significance to prevent and control the biological fouling of marine equipment in service, as well as water environment safety, marine economy and human health simultaneously. Here, an environment-friendly efficient visible-light antibacterial photocatalyst of P, Mo co-doped TiO2 nanoflower/g-C3N4 material with various defects serving as reactive sites, together with the antibacterial active Mo ion was optimized constructed. First, the one-step hydrothermal method enables the adjustable construction of P, Mo co-doped TiO2 nanoflowers, thereby improving the antibacterial performance and optimizing TiO2-based photocatalytic antibacterial materials. Among them, 0.02 P, Mo-TiO2 (added 0.02 g phosphomolybdic acid) contributes to an enhanced photogenerated active radicals production and has the greatest photocatalytic performance. The co-doping of P, Mo adjusts the band gap structure of TiO2 resulting in a narrowing of the band gap. Then, combining 0.02 P, Mo-TiO2 with two-dimensional porous nanosheet-like g-C3N4 to form 0.02 P, Mo-TiO2/g-C3N4 composite via a simple adsorption deposition method further achieves a more efficient and broad-spectrum responsive photocatalytic antibacterial performance. The 0.02 P, Mo-TiO2/g-C3N4 shows the optimal photocatalytic antibacterial performance, with the sterilization rate of Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) and Pseudomonas aeruginosa (P. aeruginosa) of 99.08 %, 98.65 % and 99.07 % respectively under visible light illumination of 300 min, which are 2.6 %, 14.4 % and 4.66 % higher than those of the TiO2/g-C3N4. The n-n heterojunctions with the gradient matched band gap structure improve the separation efficiency of photogenerated charge carriers and improves the visible-light photocatalytic performance. Besides, the Mo with an antibacterial performance of metal ion slow-releasing characteristic, similar to silver synergistically functioned during the antibacterial application. Finally, for 0.02 P, Mo-TiO2/g-C3N4, the n-n heterojunction, the increase of adsorption and active sites and the synergistic antibacterial function of Mo together enhanced the visible light photocatalytic antibacterial performance dramatically. Our work provides insights into designing efficient photocatalysts as a promising new antibacterial material for environmental applications.
WOS关键词S-SCHEME HETEROJUNCTION ; NANOTUBES ; CORROSION
资助项目Major Basic Research Project of Natural Science Foundation of Shandong Province, China[ZR2023ZD31] ; National Natural Science Foundation of China[42176049] ; National Natural Science Foundation of China[42076043] ; Chinese Academy of Sciences President's Inter-national Fellowship Initiative[2023VEA0007] ; Shandong Provincial Natural Science Foundation, China[ZR2022YQ39] ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-DQC025]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:001599732800001
出版者ELSEVIER SCIENCE SA
源URL[http://ir.qdio.ac.cn/handle/337002/203650]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Zhang, Jie; Sun, Mengmeng; Zhang, Ruiyong
作者单位1.Univ Duisburg Essen, Aquat Biotechnol, D-45141 Essen, Germany
2.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
3.Chinese Acad Sci, Inst Oceanol, State Key Lab Adv Marine Mat, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
4.Univ Min & Technol, Inst Biosci, D-09599 Freiberg, Germany
5.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Xue, Leilei,Zhang, Jie,Sun, Mengmeng,et al. An environment-friendly efficient visible-light photocatalyst of P, Mo co-doped TiO2 nanoflowers hybridized with 2D porous g-C3N4 nanosheets for the antibacterial application[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2025,1044:15.
APA Xue, Leilei.,Zhang, Jie.,Sun, Mengmeng.,Wang, Debao.,Zhang, Hui.,...&Hou, Baorong.(2025).An environment-friendly efficient visible-light photocatalyst of P, Mo co-doped TiO2 nanoflowers hybridized with 2D porous g-C3N4 nanosheets for the antibacterial application.JOURNAL OF ALLOYS AND COMPOUNDS,1044,15.
MLA Xue, Leilei,et al."An environment-friendly efficient visible-light photocatalyst of P, Mo co-doped TiO2 nanoflowers hybridized with 2D porous g-C3N4 nanosheets for the antibacterial application".JOURNAL OF ALLOYS AND COMPOUNDS 1044(2025):15.

入库方式： OAI收割

来源：海洋研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。