Enhanced low-temperature activity of Rh-Pt alloy clusters supported on TiO2/Ti nanosheets for selective catalytic reduction of NO by CO
文献类型：期刊论文
| 作者 | Yang, Liu1,2; Li, Xinyu3,4; He, Hanze3,4; Liu, Tingting3,4; Wang, Weizhen5,6; Yang, Zhiqing5,6; Li, Song3; Li, Jing3,4; Liu, Baodan3,4 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2025-06-30 |
| 卷号 | 695页码:12 |
| 关键词 | Rh-Pt alloy Cluster CO-SCR Monolithic catalyst |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2025.162824 |
| 通讯作者 | Yang, Zhiqing(yangzq34@163.com) ; Li, Jing(lijing1@mail.neu.edu.cn) ; Liu, Baodan(baodanliu@hotmail.com) |
| 英文摘要 | Achieving high catalytic activity at low temperatures in the selective catalytic reduction of NO by CO (CO-SCR) remains a significant challenge, primarily due to the inhibitory effect of O2, which hampers the NO reduction process. In this study, we designed Rh-Pt alloy clusters supported on TiO2 nanosheets to optimize the CO-SCR performance. Among the catalysts investigated, Rh1Pt1/TiO2/Ti demonstrated exceptional low-temperature catalytic performance. Under 0.15 % O2 conditions, the Rh1Pt1/TiO2/Ti catalyst achieved complete NO conversion at 180 degrees C, outperforming both Rh1/TiO2/Ti and Pt1/TiO2/Ti catalysts. Characterization results revealed the strong interaction between Rh, Pt and TiO2 optimizes electron transfer, enhances overall catalytic activity and promotes efficient adsorption and activation of both CO and NO. Specifically, Rh facilitates the adsorption and dissociation of NO, while Pt enhances CO adsorption and transformation. Based on in situ DRIFTS experiments and DFT calculations, a possible reaction mechanism for the Rh-Pt/TiO2/Ti catalyst in CO-SCR was proposed. This study provides valuable insights for the exploration and development of CO-SCR catalysts towards industrial application. |
| 资助项目 | National Natural Science Foundation of China[52202166] ; National Natural Science Foundation of China[U23A20545] ; National Natural Science Foundation of China[52331001] ; Basic and Applied Basic Research Foundation of Guangdong Province[2022A1515011170] ; Basic and Applied Basic Research Foundation of Guangdong Province[2023A1515010678] ; Fundamental Research Funds for the Central Universities[N2229002] ; Research and the Development Start-up Foundation of Foshan Graduate School of Innovation, Northeastern University, China[FSNEU20201016001] ; Research and the Development Start-up Foundation of Foshan Graduate School of Innovation, Northeastern University, China[FSNEU20201016003] ; Scientific Research Project of Foshan Talents[200076622001] ; Scientific Research Project of Foshan Talents[200076622004] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001443114400001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Basic and Applied Basic Research Foundation of Guangdong Province ; Fundamental Research Funds for the Central Universities ; Research and the Development Start-up Foundation of Foshan Graduate School of Innovation, Northeastern University, China ; Scientific Research Project of Foshan Talents |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Yang, Zhiqing; Li, Jing; Liu, Baodan |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Northeastern Univ, Sch Mat Sci & Engn, 11 Wenhua Rd, Shenyang 110819, Peoples R China 4.Northeastern Univ, Foshan Grad Sch Innovat, 2 Zhihui Rd, Foshan 528300, Peoples R China 5.Ji Hua Lab, Foshan 528200, Peoples R China 6.Foshan Univ, Foshan 528231, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Liu,Li, Xinyu,He, Hanze,et al. Enhanced low-temperature activity of Rh-Pt alloy clusters supported on TiO2/Ti nanosheets for selective catalytic reduction of NO by CO[J]. APPLIED SURFACE SCIENCE,2025,695:12. |
| APA | Yang, Liu.,Li, Xinyu.,He, Hanze.,Liu, Tingting.,Wang, Weizhen.,...&Liu, Baodan.(2025).Enhanced low-temperature activity of Rh-Pt alloy clusters supported on TiO2/Ti nanosheets for selective catalytic reduction of NO by CO.APPLIED SURFACE SCIENCE,695,12. |
| MLA | Yang, Liu,et al."Enhanced low-temperature activity of Rh-Pt alloy clusters supported on TiO2/Ti nanosheets for selective catalytic reduction of NO by CO".APPLIED SURFACE SCIENCE 695(2025):12. |
入库方式： OAI收割
来源：金属研究所
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