Functional Poly(p-terphenyl-co-4-acetylpyridine) Membranes for High-Temperature Proton Exchange Membrane Fuel-Cell Applications
文献类型：期刊论文
| 作者 | Luan, Tian1; Jin, Yaping2; Wu, Danni1; Wei, Wei3; Yang, Jingshuai2; Wang, Jin1 |
| 刊名 | ACS APPLIED POLYMER MATERIALS
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| 出版日期 | 2025-03-04 |
| 卷号 | 7期号:5页码:3224-3232 |
| 关键词 | poly( |
| ISSN号 | 2637-6105 |
| DOI | 10.1021/acsapm.4c04024 |
| 通讯作者 | Yang, Jingshuai(yjs@mail.neu.edu.cn) ; Wang, Jin(wangjin@symc.edu.cn) |
| 英文摘要 | The development of high-temperature proton exchange membranes (HT-PEMs) with low cost, simple synthetic pathways, and superior physicochemical performance is of paramount importance for their successful integration into fuel cells. Herein, we prepare HT-PEMs by grafting alkaline side-chain groups onto poly(p-terphenyl-co-4-acetylpyridine) membranes (PTAP-R), taking 2-chloromethylbenzimidazole (BIm) and (3-bromopropyl)trimethylammonium bromide (TAB) as functionalized reagents. Initially, PTAP is synthesized via a straightforward Friedel-Crafts polymerization process. For the purpose of increasing the phosphoric acid (PA) doping content along with improving conductivity, BIm or TAB with alkaline side chains is incorporated onto the PTAP backbones. Comparative analysis reveals that the PTAP-BIm membrane accomplishes an exceptional PA doping level of 289%, and the conductivity attains 122 mS/cm at 180 degrees C in nonhumidification conditions. Large amounts of PA molecules provide numerous active sites for proton transfer, leading to the development of extensive and dynamic hydrogen bonding networks along with densely interconnected transport pathways, which offer additional pathways for effective proton conduction. Furthermore, the H2-air fuel cell utilizing PTAP-BIm membrane with 289%PA achieves a peak power density of 324 mW/cm2 at 160 degrees C without backpressure. This study elucidates a cost-effective and mild approach for fabricating high-performance HT-PEMs that hold great potential in HT-PEM fuel-cell applications. |
| 资助项目 | National Natural Science Foundation of China[52403273] ; National Natural Science Foundation of China[51603031] ; Natural Science Foundation of China[2022-BS-341] ; PhD Start-up Foundation of Liaoning Province[20249072] ; Student Training Project of Shenyang Medical College |
| WOS研究方向 | Materials Science ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001437067200001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of China ; PhD Start-up Foundation of Liaoning Province ; Student Training Project of Shenyang Medical College |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Yang, Jingshuai; Wang, Jin |
| 作者单位 | 1.Shenyang Med Coll, Sch Pharm, Shenyang 110034, Peoples R China 2.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luan, Tian,Jin, Yaping,Wu, Danni,et al. Functional Poly(p-terphenyl-co-4-acetylpyridine) Membranes for High-Temperature Proton Exchange Membrane Fuel-Cell Applications[J]. ACS APPLIED POLYMER MATERIALS,2025,7(5):3224-3232. |
| APA | Luan, Tian,Jin, Yaping,Wu, Danni,Wei, Wei,Yang, Jingshuai,&Wang, Jin.(2025).Functional Poly(p-terphenyl-co-4-acetylpyridine) Membranes for High-Temperature Proton Exchange Membrane Fuel-Cell Applications.ACS APPLIED POLYMER MATERIALS,7(5),3224-3232. |
| MLA | Luan, Tian,et al."Functional Poly(p-terphenyl-co-4-acetylpyridine) Membranes for High-Temperature Proton Exchange Membrane Fuel-Cell Applications".ACS APPLIED POLYMER MATERIALS 7.5(2025):3224-3232. |
入库方式： OAI收割
来源：金属研究所
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