Electrocatalytic CO2 reduction for the selective production of liquid
文献类型：期刊论文
| 作者 | Ji, Jiapeng1; Chen, Junnan1; Xiong, Juxia1; Zhang, Xiaolong1,2; Cheng, Hui-Ming1,2,3 |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
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| 出版日期 | 2025-04-01 |
| 卷号 | 103页码:568-600 |
| 关键词 | Electrocatalytic CO2 reduction Geometry and electronic structure Parameters and system configurations Liquid oxygenates |
| ISSN号 | 2095-4956 |
| DOI | 10.1016/j.jechem.2024.12.022 |
| 通讯作者 | Zhang, Xiaolong(xl.zhang@siat.ac.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn) |
| 英文摘要 | Electrocatalytic CO2 reduction (ECR) to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels. Among various ECR products, liquid oxygenates (Oxys) are especially attractive due to their high energy density, high safety and transportability that could be adapted to the existing infrastructure and transportation system. However, efficiently generating these highly reduced oxygen-containing products by ECR remains challenging due to the complexity of coupled proton and electron transfer processes. In recent years, in-depth studies of reaction mechanisms have advanced the design of catalysts and the regulation of reaction systems for ECR to produce Oxys. Here, by focusing on the production of typical Oxys, such as methanol, acetic acid, ethanol, acetone, n-propanol, and isopropanol, we outline various reaction paths and key intermediates for the electrochemical conversion of CO2 into these target products. We also summarize the current research status and recent advances in catalysts based on their elemental composition, and consider recent studies on the change of catalyst geometry and electronic structure, as well as the optimization of reaction systems to increase ECR performance. Finally, we analyze the challenges in the field of ECR to Oxys and provide an outlook on future directions for high-efficiency catalyst prediction and design, as well as the development of advanced reaction systems. (c) 2024 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights are reserved, including those for text and data mining, AI training, and similar technologies. |
| 资助项目 | National Natural Science Foundation of China[52201237] ; Talent Introduction Project of Chinese Academy of Sciences[E344011] ; Shenzhen High Level Talent Team Project[KQTD2022110109364705] ; Joint Research Project of China Merchants Group and SIAT[E2Z1521] ; Cross Institute Joint Research Youth Team Project of SIAT[E25427] ; National Natural Science Foundation of China[52402136] ; China Postdoctoral Science Foundation[E325281005] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001398813100001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Talent Introduction Project of Chinese Academy of Sciences ; Shenzhen High Level Talent Team Project ; Joint Research Project of China Merchants Group and SIAT ; Cross Institute Joint Research Youth Team Project of SIAT ; National Natural Science Foundation of China ; China Postdoctoral Science Foundation |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhang, Xiaolong; Cheng, Hui-Ming |
| 作者单位 | 1.Chinese Acad Sci, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen 518055, Guangdong, Peoples R China 2.Shenzhen Univ Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen 518055, Guangdong, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Jiapeng,Chen, Junnan,Xiong, Juxia,et al. Electrocatalytic CO2 reduction for the selective production of liquid[J]. JOURNAL OF ENERGY CHEMISTRY,2025,103:568-600. |
| APA | Ji, Jiapeng,Chen, Junnan,Xiong, Juxia,Zhang, Xiaolong,&Cheng, Hui-Ming.(2025).Electrocatalytic CO2 reduction for the selective production of liquid.JOURNAL OF ENERGY CHEMISTRY,103,568-600. |
| MLA | Ji, Jiapeng,et al."Electrocatalytic CO2 reduction for the selective production of liquid".JOURNAL OF ENERGY CHEMISTRY 103(2025):568-600. |
入库方式： OAI收割
来源：金属研究所
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