Zinc Affinity and Hydrogen Evolution Trade-Off for Homogenous Zn Deposition in Reversible Zn Ion Batteries
文献类型：期刊论文
| 作者 | Yi, Zhehan1,2; Jia, Jingjing1; Yang, Jin-Lin3; Yu, Jin1; Tan, Shandong1; Li, Jia4; Liu, Xiaoqing1; Sang, Zhiyuan1; Yin, Lichang5; Liu, Huan6 |
| 刊名 | SMALL
 |
| 出版日期 | 2024-12-01 |
| 卷号 | 20期号:50页码:9 |
| 关键词 | Cu-Sn nanowire dendrite hydrogen evolution reaction zinc anode zinc ion batteries |
| ISSN号 | 1613-6810 |
| DOI | 10.1002/smll.202405300 |
| 通讯作者 | Liang, Ji(liangji@tju.edu.cn) ; Hou, Feng(houf@tju.edu.cn) |
| 英文摘要 | Zn ion batteries (ZIBs) are promising for large-scale energy storage but their practical application is plagued by inhomogeneous Zn deposition. Despite much effort, the harm of simultaneous hydrogen evolution reaction (HER) during plating to Zn deposition, has not received sufficient studies. Herein, Sn-modified Cu nanowires (Sn@CuNWs) with Sn-Cu core-shell nanostructure to achieve uniform Zn deposition by zinc affinity-HER tendency trade-off are fabricated. Confirmed by both theoretical calculation and practical characterization, the nanowires with high zinc affinity and large deposition sites facilitate Zn deposition, while the enlarged HER tendency harmful to Zn plating is inhibited by Sn nanoshell. Therefore, the Zn deposited Sn@CuNWs anode delivers a long lifespan of 800 h at 5 mA cm(-2), and the full cell exhibits a high capacity of 294.4 mAh g(-1) at 5 A g(-1) and a high capacity retention of 97.8% after 2500 cycles. This work reveals the importance of HER regulation for reversible Zn deposition, which should be noticed in further research. |
| 资助项目 | National Natural Science Foundation of China[21905202] ; National Natural Science Foundation of China[22179093] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001397088000032 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liang, Ji; Hou, Feng |
| 作者单位 | 1.Tianjin Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China 2.Nanyang Technol Univ, Grad Coll, Interdisciplinary Grad Programme Collaborat Initi, Singapore 637371, Singapore 3.Nanyang Technol Univ, Sch Phys & Math Sci, Singapore 637371, Singapore 4.Nanyang Technol Univ, Rolls Royce NTU Corporate Lab, Singapore 639798, Singapore 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 6.Xian Univ Sci & Technol, Coll Mat Sci & Engn, Xian 710054, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, Zhehan,Jia, Jingjing,Yang, Jin-Lin,et al. Zinc Affinity and Hydrogen Evolution Trade-Off for Homogenous Zn Deposition in Reversible Zn Ion Batteries[J]. SMALL,2024,20(50):9. |
| APA | Yi, Zhehan.,Jia, Jingjing.,Yang, Jin-Lin.,Yu, Jin.,Tan, Shandong.,...&Hou, Feng.(2024).Zinc Affinity and Hydrogen Evolution Trade-Off for Homogenous Zn Deposition in Reversible Zn Ion Batteries.SMALL,20(50),9. |
| MLA | Yi, Zhehan,et al."Zinc Affinity and Hydrogen Evolution Trade-Off for Homogenous Zn Deposition in Reversible Zn Ion Batteries".SMALL 20.50(2024):9. |
入库方式： OAI收割
来源：金属研究所
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