中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Anticorrosive behavior of polyurethane coating containing hybrid attapulgite pigment

文献类型:期刊论文

作者Xu, Hao1,2,3; Ali, Mustehsin2,4; Wu, Bin1; Shi, Hongwei1,2; Gu, Songhua2; Han, En-Hou2,3,5
刊名PROGRESS IN ORGANIC COATINGS
出版日期2025-03-01
卷号200页码:10
关键词Polyurethane coating Attapulgite 2-Mercaptobenzothiazole Anticorrosive pigment EIS Aluminum alloy
ISSN号0300-9440
DOI10.1016/j.porgcoat.2024.109035
通讯作者Shi, Hongwei(hwshi@sut.edu.cn)
英文摘要This study introduced new anticorrosive pigments by modigying attapulgite (ATP) via a silane coupling agent. An organic corrosion inhibitor, 2-mercaptobenzothiazole (MBT) was loaded on the surface of modified-ATP. The morphologies and compositional structures of ATP@MBT were characterized utilizing Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). UV-vis spectroscopy was used to study the loading and release behavior of MBT. ATP@MBT was incorporated into a polyurethane coating and the corrosion resistance of the coatings was investigated. The results demonstrate that ATP@MBT was well dispersed, with MBT loading capacity up to 4.8 wt% and release rate up to 97.5 % at pH = 3. The results of electrochemical impedance spectra (EIS) and salt spray tests show that the addition of ATP@MBT enhances the corrosion resistance of the coatings. There are two explanations for the protective mechanism of the coatings containing ATP@MBT. The barrier function of ATP enhances the shielding ability of the integral coatings. When the coating is scratched, MBT loaded on ATP is released on the exposed region and forms an adsorption film on the aluminum alloy surface to protect the substrate.
资助项目National Natural Science Foundation of China[52171809] ; National Natural Science Foundation of China[51571202] ; Liaoning Province International Science and Technology Cooperation Program Project[2024JH2/101900013] ; Key Program of Basic Research Projects of Liaoning Provincial Department of Education[JYTZD2023114]
WOS研究方向Chemistry ; Materials Science
语种英语
WOS记录号WOS:001412100500001
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China ; Liaoning Province International Science and Technology Cooperation Program Project ; Key Program of Basic Research Projects of Liaoning Provincial Department of Education
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Shi, Hongwei
作者单位1.Shenyang Univ Technol, Sch Mat Sci & Engn, Shenyang 110870, Peoples R China
2.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
3.Univ Sci & Technol Beijing, Natl Ctr Mat Serv Safety, Beijing 100083, Peoples R China
4.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
5.Inst Corros Sci & Technol, Guangzhou 510530, Peoples R China
推荐引用方式
GB/T 7714
Xu, Hao,Ali, Mustehsin,Wu, Bin,et al. Anticorrosive behavior of polyurethane coating containing hybrid attapulgite pigment[J]. PROGRESS IN ORGANIC COATINGS,2025,200:10.
APA Xu, Hao,Ali, Mustehsin,Wu, Bin,Shi, Hongwei,Gu, Songhua,&Han, En-Hou.(2025).Anticorrosive behavior of polyurethane coating containing hybrid attapulgite pigment.PROGRESS IN ORGANIC COATINGS,200,10.
MLA Xu, Hao,et al."Anticorrosive behavior of polyurethane coating containing hybrid attapulgite pigment".PROGRESS IN ORGANIC COATINGS 200(2025):10.

入库方式: OAI收割

来源:金属研究所

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