Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis
文献类型：期刊论文
| 作者 | Li, Feng1; Yao, Canglang1; Jeon, Jong-Pil2; Han, Gao-Feng2; Shin, Tae Joo4; Han, Ali5; Fu, Zhengping3; Lu, Yalin3; Baek, Jong-Beom2 |
| 刊名 | ACS NANO
 |
| 出版日期 | 2023-11-27 |
| 卷号 | 17期号:23页码:24282-24289 |
| 关键词 | catalyst active sites electrochemistry hydrogen evolution reaction energy conversion |
| ISSN号 | 1936-0851 |
| DOI | 10.1021/acsnano.3c09806 |
| 通讯作者 | Li, Feng(li_feng@fudan.edu.cn) ; Han, Ali(alhan@imr.ac.cn) ; Baek, Jong-Beom(jbbaek@unist.ac.kr) |
| 英文摘要 | Efficient and stable catalysts are highly desired for the electrochemical conversion of hydrogen, oxygen, and water molecules, processes which are crucial for renewable energy conversion and storage technologies. Herein, we report the development of hollow nitrogenated carbon sphere (HNC) dispersed rhodium (Rh) single atoms (Rh1HNC) as an efficient catalyst for bifunctional catalysis. The Rh1HNC was achieved by anchoring Rh single atoms in the HNC matrix with an Rh-N3C1 configuration, via a combination of in situ polymerization and carbonization approach. Benefiting from the strong metal atom-support interaction (SMASI), the Rh and C atoms can collaborate to achieve robust electrochemical performance toward both the hydrogen evolution and oxygen reduction reactions in acidic media. This work not only provides an active site with favorable SMASI for bifunctional catalysis but also brings a strategy for the design and synthesis of efficient and stable bifunctional catalysts for diverse applications. |
| 资助项目 | Fudan University[JIH2203004Y] ; Fudan University[QXH2203003] ; Fudan University[2014R1A3A2069102] ; National Natural Science Foundation of China ; National Research Foundation (NRF) of Korea |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001125127900001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Fudan University ; Fudan University ; National Natural Science Foundation of China ; National Research Foundation (NRF) of Korea |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Feng; Han, Ali; Baek, Jong-Beom |
| 作者单位 | 1.Fudan Univ, Lab Adv Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Handan 220, Shanghai 200433, Peoples R China 2.Ulsan Natl Inst Sci & Technol UNIST, Ctr Dimens Controllable Organ Frameworks, Sch Energy & Chem Engn, Ulsan 44919, South Korea 3.Univ Sci & Technol China, Anhui Lab Adv Photon Sci & Technol, Hefei 230026, Anhui, Peoples R China 4.Ulsan Natl Inst Sci & Technol, UNIST Cent Res Facil, Ulsan 44919, South Korea 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Feng,Yao, Canglang,Jeon, Jong-Pil,et al. Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis[J]. ACS NANO,2023,17(23):24282-24289. |
| APA | Li, Feng.,Yao, Canglang.,Jeon, Jong-Pil.,Han, Gao-Feng.,Shin, Tae Joo.,...&Baek, Jong-Beom.(2023).Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis.ACS NANO,17(23),24282-24289. |
| MLA | Li, Feng,et al."Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis".ACS NANO 17.23(2023):24282-24289. |
入库方式： OAI收割
来源：金属研究所
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