Highly selective hydrogen peroxide electrosynthesis on copper phthalocyanine: interface engineering with an azo-polymer
文献类型：期刊论文
| 作者 | Sun, Zebang1; Lu, Xingyu2,3; Wang, Xuanzhi1,2; Wang, Di4; Luan, Jian5; Liu, Yu1; Qi, Wei2,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2024-01-29 |
| 页码 | 8 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/d3ta06728a |
| 通讯作者 | Lu, Xingyu(xylu17s@imr.ac.cn) ; Liu, Yu(liuyu@syuct.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) |
| 英文摘要 | The two-electron oxygen reduction reaction provides a new green route for the sustainable production of H2O2, which is cost-effective, less energy-intensive and environmentally friendly compared to the industrial anthraquinone method. However, the activity and stability of the catalyst is still in urgent need of improvement. Herein, the electrode-electrolyte (solid-liquid) interface was adjusted by surface modification of a catalyst, and the modified CuPc-NO2 catalyst with azo molecules exhibited an improved selectivity of H2O2 by 30-50%. Furthermore, the electrode surface was further modified by doping F into the azo molecule to enhance the HO2-desorption property of the catalyst. The proposed CuPc-TAP-F catalyst showed a 98% selectivity of H2O2 with a stability of 40 h and a wide potential window of 0.8 VRHE (>= 90% selectivity), reaching a relatively high level in the field of H2O2 electrosynthesis from the point of view of both efficiency and stability. The electrode-electrolyte interface was adjusted by azo molecule modification to improve the desorption of HO2-. The H2O2 selectivity and stability of CuPc-TAP-F in a wide potential window is a higher level in the field of H2O2 electrosynthesis. |
| 资助项目 | National Natural Science Foundation of China[LJKMZ20220793] ; National Natural Science Foundation of China[LJKMZ20220795] ; Liaoning Provincial Department of Education Fund[2023JH2/101300231] ; Applied Basic Research Program of Liaoning Science and Technology Department[22072163] ; NSFC of China[2020-YQ-02] ; Natural Science Foundation of Liaoning Province of China[Foundation-BWLCF202113] ; China Baowu Low Carbon Metallurgy Innovation[2023-PY13] ; IMR Innovation Fund |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001151626300001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Liaoning Provincial Department of Education Fund ; Applied Basic Research Program of Liaoning Science and Technology Department ; NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation ; IMR Innovation Fund |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Lu, Xingyu; Liu, Yu; Qi, Wei |
| 作者单位 | 1.Shenyang Univ Chem Technol, Coll Sci, Shenyang 110142, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Shenyang Pharmaceut Univ, Sch Pharm, Benxi 117004, Peoples R China 5.Northeastern Univ, Coll Sci, Shenyang 110819, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Zebang,Lu, Xingyu,Wang, Xuanzhi,et al. Highly selective hydrogen peroxide electrosynthesis on copper phthalocyanine: interface engineering with an azo-polymer[J]. JOURNAL OF MATERIALS CHEMISTRY A,2024:8. |
| APA | Sun, Zebang.,Lu, Xingyu.,Wang, Xuanzhi.,Wang, Di.,Luan, Jian.,...&Qi, Wei.(2024).Highly selective hydrogen peroxide electrosynthesis on copper phthalocyanine: interface engineering with an azo-polymer.JOURNAL OF MATERIALS CHEMISTRY A,8. |
| MLA | Sun, Zebang,et al."Highly selective hydrogen peroxide electrosynthesis on copper phthalocyanine: interface engineering with an azo-polymer".JOURNAL OF MATERIALS CHEMISTRY A (2024):8. |
入库方式： OAI收割
来源：金属研究所
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