Well-dispersed FeNi nanoparticles embedded in N-doped carbon nanofiber membrane as a self-supporting and binder-free anode for lithium-ion batteries
文献类型：期刊论文
| 作者 | Li, Xiaoqiang1,2; Guan, Guangguang3,4; Cheng, Bingjie1; Zhang, Xueke1; Zhang, Kaiyin5; Xiang, Jun1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2024-01-16 |
| 页码 | 9 |
| ISSN号 | 2050-7526 |
| DOI | 10.1039/d3tc03383j |
| 通讯作者 | Xiang, Jun() |
| 英文摘要 | Flexible energy storage systems and wearable electronics are revolutionary and prospective technologies for various photoelectronic equipment. Herein, a three-dimensional (3D) nanoarchitecture of N-doped carbon nanofibers (NCNFs) with in situ incorporation of FeNi alloy nanoparticles (FeNi@NCNF) was fabricated via electrospinning, followed by an annealing process. The microstructure observations demonstrate that the FeNi nanoparticles with a size in the range 3-48 nm are homogeneously anchored on a carbon substrate. Benefitting from the advantages of flexible self-supporting of 3D NCNFs and a high electronic conducting FeNi alloy, the optimal FeNi@NCNF electrode exhibited good electrochemical properties with a high reversible charge capacity (406.5 mA h g-1 at 100 mA g-1 after 100 cycles), high coulombic efficiency (coulombic efficiency of 99.9% after 100 cycles), long service life, and superior rate properties (204.6 mA h g-1 at 1 A g-1). These superior electrochemical properties could be attributed to the unique construction of fine FeNi nanoparticles uniformly embedded in NCNFs, which significantly enhanced the utilization factor of the active materials, promoting the transfer of electrons and lithium-ions, and restraining FeNi nanoparticles pulverization/agglomeration during long-term lithiation/delithiation processes. It is reasonable to believe that the flexible self-supporting FeNi@NCNF electrode can be immediately employed in flexible cells without additional additives, which fulfills excellent flexibility and retains good lithium storage properties during physical deformations. The as-prepared flexible FeNi@NCNF is directly utilized as an electrode in LIBs without the use of any binders or conductive additives and exhibits superior electrochemical performance. |
| 资助项目 | Natural Science Foundation of Fujian Province[2020J01393] ; Natural Science Foundation of Fujian Province of China[KYCX23-3823] ; Postgraduate Research and Practice Innovation Program of Jiangsu Province of China |
| WOS研究方向 | Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001151632400001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Natural Science Foundation of Fujian Province ; Natural Science Foundation of Fujian Province of China ; Postgraduate Research and Practice Innovation Program of Jiangsu Province of China |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xiang, Jun |
| 作者单位 | 1.Jiangsu Univ Sci & Technol, Sch Sci, Zhenjiang 212100, Peoples R China 2.Beijing Univ Technol, Inst Mat Sci & Engn, Beijing 100124, Peoples R China 3.Inst Met Sci & Technol, Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 5.Wuyi Univ, Coll Mech & Elect Engn, Wuyishan 354300, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiaoqiang,Guan, Guangguang,Cheng, Bingjie,et al. Well-dispersed FeNi nanoparticles embedded in N-doped carbon nanofiber membrane as a self-supporting and binder-free anode for lithium-ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY C,2024:9. |
| APA | Li, Xiaoqiang,Guan, Guangguang,Cheng, Bingjie,Zhang, Xueke,Zhang, Kaiyin,&Xiang, Jun.(2024).Well-dispersed FeNi nanoparticles embedded in N-doped carbon nanofiber membrane as a self-supporting and binder-free anode for lithium-ion batteries.JOURNAL OF MATERIALS CHEMISTRY C,9. |
| MLA | Li, Xiaoqiang,et al."Well-dispersed FeNi nanoparticles embedded in N-doped carbon nanofiber membrane as a self-supporting and binder-free anode for lithium-ion batteries".JOURNAL OF MATERIALS CHEMISTRY C (2024):9. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。