Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
文献类型：期刊论文
| 作者 | Mu, Jianjia1; Gao, Xuan-Wen1; Yu, Tong2; Zhao, Lu-Kang1; Luo, Wen-Bin1; Yang, Huicong2; Liu, Zhao-Meng1; Sun, Zhenhua2; Gu, Qin-Fen1,3; Li, Feng2 |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2024-02-12 |
| 页码 | 17 |
| 关键词 | electrocatalyst design electrochemical ammonia synthesis nitrate reduction reaction nitrogen reduction reaction |
| DOI | 10.1002/advs.202308979 |
| 通讯作者 | Luo, Wen-Bin(luowenbin@smm.neu.edu.cn) ; Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | Ammonia, a vital component in the synthesis of fertilizers, plastics, and explosives, is traditionally produced via the energy-intensive and environmentally detrimental Haber-Bosch process. Given its considerable energy consumption and significant greenhouse gas emissions, there is a growing shift toward electrocatalytic ammonia synthesis as an eco-friendly alternative. However, developing efficient electrocatalysts capable of achieving high selectivity, Faraday efficiency, and yield under ambient conditions remains a significant challenge. This review delves into the decades-long research into electrocatalytic ammonia synthesis, highlighting the evolution of fundamental principles, theoretical descriptors, and reaction mechanisms. An in-depth analysis of the nitrogen reduction reaction (NRR) and nitrate reduction reaction (NitRR) is provided, with a focus on their electrocatalysts. Additionally, the theories behind electrocatalyst design for ammonia synthesis are examined, including the Gibbs free energy approach, Sabatier principle, d-band center theory, and orbital spin states. The review culminates in a comprehensive overview of the current challenges and prospective future directions in electrocatalyst development for NRR and NitRR, paving the way for more sustainable methods of ammonia production. This review delves into the decades-long research into electrocatalytic ammonia synthesis, highlighting the evolution of fundamental principles, theoretical descriptors, and reaction mechanisms and paving the way for more sustainable methods of ammonia production. image |
| 资助项目 | National Natural Science Foundation of China ; LiaoNing Revitalization Talents Program[XLYC2007155] ; [52272194] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001160445500001 |
| 出版者 | WILEY |
| 资助机构 | National Natural Science Foundation of China ; LiaoNing Revitalization Talents Program |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Luo, Wen-Bin; Li, Feng |
| 作者单位 | 1.Northeastern Univ, Inst Energy Electrochem & Urban Mines Met, Sch Met, Shenyang 110819, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Australian Synchrotron ANSTO, 800 Blackburn Rd, Clayton, Vic 3168, Australia |
| 推荐引用方式 GB/T 7714 | Mu, Jianjia,Gao, Xuan-Wen,Yu, Tong,et al. Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design[J]. ADVANCED SCIENCE,2024:17. |
| APA | Mu, Jianjia.,Gao, Xuan-Wen.,Yu, Tong.,Zhao, Lu-Kang.,Luo, Wen-Bin.,...&Li, Feng.(2024).Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design.ADVANCED SCIENCE,17. |
| MLA | Mu, Jianjia,et al."Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design".ADVANCED SCIENCE (2024):17. |
入库方式： OAI收割
来源：金属研究所
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