中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical dissolution of MCrAlY coatings and oxide layers on Ni-based superalloys in 3.5% NaCl and aqua-regia solutions

文献类型:期刊论文

作者Wang, Yuemiao1,2; Yang, Yanhong2; Qu, Jinglong3; Cui, Chuanyong2
刊名INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
出版日期2024-02-01
卷号19期号:2页码:13
关键词Superalloy Oxidation Coating Electrochemical corrosion
ISSN号1452-3981
DOI10.1016/j.ijoes.2023.100451
通讯作者Yang, Yanhong(yhyang@imr.ac.cn) ; Cui, Chuanyong(chycui@imr.ac.cn)
英文摘要Superalloys are widely used for aerospace industry. At the same time, more and more superalloy scraps are produced. Therefore, the recycling and reuse of superalloy scraps is of great significance. Purification smelting after surface impurity removal is an application trend of superalloy regeneration technology. Electrochemical methods can be used to remove metal impurities such as oxide layers and coatings. The electrochemical dissolution behavior of a Ni-based superalloy with coating and oxide layer has been studied in 3.5 wt% NaCl solution and aqua regia solution. The results show that pitting corrosion occurs on the surface of the alloy in 3.5 wt% NaCl solution, forming a "occlude corrosion cell" and leaving a lot of pitting corrosion. The oxide layer itself is a passivation film with high stability in 3.5 wt% NaCl solution. However, in aqua regia solution, the alloy underwent strong corrosion, and the surface coating and oxide layer of the alloy fell off in large quantities. The results show that the oxide layer like a "coating" with high corrosion resistance, which prevents the reaction between the alloy and the electrolyte. However, due to the poor density of the oxide layer, the electrolyte flows into the alloy matrix along the oxide layer gap, and electrochemical reaction occurs with the matrix. In aqua regia electrolyte, the oxide layer is thus peeled off. In this study, the dissolution behavior of the coating and the oxide layer in different electrolyte solutions was clarified, and the dissolution model of the coating on the alloy surface and the spalling mechanism of the oxide layer were established.
资助项目National Key R & D Pro- gram of China[2021YFB3700401] ; National Science and Technology Major Project[Y2019 -VII -0011-0151]
WOS研究方向Electrochemistry
语种英语
WOS记录号WOS:001170941100001
出版者ELSEVIER
资助机构National Key R & D Pro- gram of China ; National Science and Technology Major Project
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Yang, Yanhong; Cui, Chuanyong
作者单位1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
2.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
3.Gaona Aero Mat Co Ltd, Beijing 100081, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yuemiao,Yang, Yanhong,Qu, Jinglong,et al. Electrochemical dissolution of MCrAlY coatings and oxide layers on Ni-based superalloys in 3.5% NaCl and aqua-regia solutions[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2024,19(2):13.
APA Wang, Yuemiao,Yang, Yanhong,Qu, Jinglong,&Cui, Chuanyong.(2024).Electrochemical dissolution of MCrAlY coatings and oxide layers on Ni-based superalloys in 3.5% NaCl and aqua-regia solutions.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,19(2),13.
MLA Wang, Yuemiao,et al."Electrochemical dissolution of MCrAlY coatings and oxide layers on Ni-based superalloys in 3.5% NaCl and aqua-regia solutions".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 19.2(2024):13.

入库方式: OAI收割

来源:金属研究所

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