Nitrogen, phosphorus, and sulfur co-doped carbon nanotubes/melamine foam composite electrode for high-performance vanadium redox flow battery
文献类型：期刊论文
| 作者 | Zhang, Xihao1,2; Liu, Lansong1,2; Hou, Shaoyu1; Zhou, Qi1,3; Zhang, Yanbo1,2; Chen, Xuehui4; Pu, Nianwen5; Liu, Jianguo1; Yan, Chuanwei1 |
| 刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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| 出版日期 | 2024-08-10 |
| 卷号 | 190页码:127-134 |
| 关键词 | N P and S co-doped Carbon nanotubes Melamine foam Vanadium redox flow battery Electrode |
| ISSN号 | 1005-0302 |
| DOI | 10.1016/j.jmst.2023.12.029 |
| 通讯作者 | Liu, Jianguo(jgliu@imr.ac.cn) |
| 英文摘要 | The high cost and complex modification process of carbon felt electrodes limits its further popularization in vanadium redox flow batteries (VFBs). By introducing low-cost melamine foam, nitrogen, phosphorus, and sulfur co-doped carbon nanotubes/ melamine foam composite electrode (NPS-CNTs-CMF) is designed and fabricated via immersing melamine foam in a solution containing N, P, and S co-doped CNTs. The integration of modified CNTs significantly enhances the conductivity and hydrophilicity of the electrode. Moreover, the composite electrode also demonstrates outstanding electrocatalytic activity owing to the heteroatom doping that further inspired the electrocatalytic activity of CNTs. Density function theory calculations further uncover that introducing heteroatoms on CNTs not only promotes the adsorption of vanadium ions but also facilitates the electron transfer between vanadium ions and MF substrate. As a result, the battery loading with NPS-CNTs-CMF exhibits excellent battery performance, achieving energy efficiency of 80.12 % at 300 mA cm-2 . Additionally, the long-term cycling stability is attained over 200 consecutive charge-discharge cycles at 300 mA cm-2 . This study provides a novel melamine foam material with low cost and simple modification, and this new composite structure stimulates the development of high-performance electrodes in VFBs. (c) 2024 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
| 资助项目 | National Key R&D Program of China[2022YFB2404901] ; National Natural Science Foundation of China[21975267] ; Central Guidance on Local Science and Technology Development Fund of Liaoning Province[2022JH6/100100001] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001181481100001 |
| 出版者 | JOURNAL MATER SCI TECHNOL |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Central Guidance on Local Science and Technology Development Fund of Liaoning Province |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Jianguo |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China 4.Cent Iron & Steel Res Inst Co Ltd, Beijing 100081, Peoples R China 5.Sichuan Xingming Energy & Environm Protect Technol, Chengdu 610100, Sichuan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xihao,Liu, Lansong,Hou, Shaoyu,et al. Nitrogen, phosphorus, and sulfur co-doped carbon nanotubes/melamine foam composite electrode for high-performance vanadium redox flow battery[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2024,190:127-134. |
| APA | Zhang, Xihao.,Liu, Lansong.,Hou, Shaoyu.,Zhou, Qi.,Zhang, Yanbo.,...&Yan, Chuanwei.(2024).Nitrogen, phosphorus, and sulfur co-doped carbon nanotubes/melamine foam composite electrode for high-performance vanadium redox flow battery.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,190,127-134. |
| MLA | Zhang, Xihao,et al."Nitrogen, phosphorus, and sulfur co-doped carbon nanotubes/melamine foam composite electrode for high-performance vanadium redox flow battery".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 190(2024):127-134. |
入库方式： OAI收割
来源：金属研究所
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