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Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials

文献类型：期刊论文

作者Wang, Zhenxing1,2,4; Li, Linqing1; Sun, Zhenhua2,3; Tang, Pei2,3; Hu, Guangjian2; Tan, Jun1,4; Li, Feng2,3
刊名PROGRESS IN MATERIALS SCIENCE
出版日期2024-06-01
卷号143页码:52
关键词Layered transition oxide cathode materials Structural stability Phase transition Bulk element doping Surface engineering
ISSN号0079-6425
DOI10.1016/j.pmatsci.2024.101247
通讯作者Tan, Jun(tanjun@jihualab.ac.cn) ; Li, Feng(fli@imr.ac.cn)
英文摘要A comprehensive understanding of the relationship between the structure (electron/bulk/surface structures) and redox chemistry in the cathodes was discussed in this Review. First, the attention is given to the comparison of different layered Li-Co-Ni-Mn oxide cathodes, especially the bulk atomic configuration (Section 2.1). Second, corresponding to the distinct layered structure, the electronic structures, Fermi level energies of different redox couples are introduced (Section 2.2). The structural failures induced by the redox chemistry at the deep lithiation state, including bulk phase transition, surface structure degradation, as well as the resulting cracking, cation mixing, oxygen release, dissolution of metal cations, voltage fading and low initial Coulombic efficiency, are discussed (Section 3.1-3.3). Correspondingly, the strategies for stabilizing the structural stability by regulating the redox activity, including bulk atomic doping design, surface engineering, cations mixing, particle morphology, oxygen vacancy and oxygen stacking type, are summarized (Section 4.1-4.3). The advanced characterization techniques, such as X-ray, electron, neutron and nuclear magnetic resonance techniques, are summarized for detecting the cationic/anionic charge state (Section 5.1-5.4). In the last section (Section 6), the promising strategies and future perspectives are highlighted to propel significant breakthroughs in developing high-energy-density LIBs.
资助项目National Natural Science Foundation of China[22209055] ; National Natural Science Foundation of China[22379151] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; China Postdoctoral Science Foundation[2022M721330] ; Foshan Postdoctoral Science Foundation[X221081MS210] ; Key R & D Plan of Jihua Laboratory[X200191TL200] ; National Key R & D Program of China[2022YFB3803400] ; National Key R & D Program of China[2021YFB3800300] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; Liaoning Revitalization Talents Program[XLYC2007080]
WOS研究方向Materials Science
语种英语
WOS记录号WOS:001186219100001
出版者PERGAMON-ELSEVIER SCIENCE LTD
资助机构National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Foshan Postdoctoral Science Foundation ; Key R & D Plan of Jihua Laboratory ; National Key R & D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Liaoning Revitalization Talents Program
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Tan, Jun; Li, Feng
作者单位1.Ji Hua Lab, Foshan 528000, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
4.Foshan Univ, Foshan 528000, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Zhenxing,Li, Linqing,Sun, Zhenhua,et al. Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials[J]. PROGRESS IN MATERIALS SCIENCE,2024,143:52.
APA Wang, Zhenxing.,Li, Linqing.,Sun, Zhenhua.,Tang, Pei.,Hu, Guangjian.,...&Li, Feng.(2024).Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials.PROGRESS IN MATERIALS SCIENCE,143,52.
MLA Wang, Zhenxing,et al."Advances and perspectives in understanding the structure-redox relationship of layered Li-Co-Ni-Mn oxide cathode materials".PROGRESS IN MATERIALS SCIENCE 143(2024):52.

入库方式： OAI收割

来源：金属研究所

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