Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction
文献类型：期刊论文
| 作者 | Liu, Jie1,2; Zhong, Xia2,3; Gao, Li2,3; Zhang, Ying2,4; Wang, Ziru1,2; Zhang, Xia1; Zhang, Bingsen2,3 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2024-06-30 |
| 卷号 | 659页码:8 |
| 关键词 | Suzuki-Miyaura reaction Palladium Zeolite Acid sites |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2024.159904 |
| 通讯作者 | Zhang, Xia(xzhang@mail.neu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) |
| 英文摘要 | The Suzuki-Miyaura reaction is one of the most effective routes for the construction of carbon-carbon bonds, due to the obvious advantages of mild reaction conditions, wide range of functional group tolerance, simplicity of operation, and environmental friendliness. However, these reactions highly depend on the development of the active and stable catalysts. Herein, the hollow hexagonal prismatic silicalite-1 (HS-1) zeolite-supported palladium nanoparticles (Pd NPs) were synthesized and applied as a catalyst in Suzuki-Miyaura reaction. The experimental results show that 2.0Pd/HS-1 is an efficient and stable catalyst, which can achieve a high conversion rate (>99.9 %) in a short time (45 min) and can be recycled. Further studies show that 2.0Pd/HS-1 has abundant mesopores, which are favorable for exposing more active sites and promoting the transfer of reactants around the catalysts, thus improving the contact opportunities between the catalysts and the feedstock. Moreover, its proper acid sites as well as metal-zeolite interactions can modulate the electronic state of Pd, and thus improve the conversion of bromobenzene. This work provides new insights into the design, synthesis and applications of highly efficient hollow silicalite-1 zeolite loaded metal catalysts. |
| 资助项目 | National Natural Science Foundation of China[52161145403] ; National Natural Science Foundation of China[22072164] ; Research Fund of Shenyang National Laboratory for Materials Science |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001215195600001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Research Fund of Shenyang National Laboratory for Materials Science |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhang, Xia; Zhang, Bingsen |
| 作者单位 | 1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 4.Liaoning Petrochem Univ, Sch Petrochem Engn, Fushun 113001, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jie,Zhong, Xia,Gao, Li,et al. Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction[J]. APPLIED SURFACE SCIENCE,2024,659:8. |
| APA | Liu, Jie.,Zhong, Xia.,Gao, Li.,Zhang, Ying.,Wang, Ziru.,...&Zhang, Bingsen.(2024).Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction.APPLIED SURFACE SCIENCE,659,8. |
| MLA | Liu, Jie,et al."Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction".APPLIED SURFACE SCIENCE 659(2024):8. |
入库方式： OAI收割
来源：金属研究所
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