中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Novel carbon coating source for better LiMn0.6Fe0.4PO4/C materials

文献类型:期刊论文

作者Liu, Guoqiang1,2; Liu, Fushuang2; Wang, Qingxiang2; Liu, Guangyin3; Wen, Lei4
刊名IONICS
出版日期2024-05-08
页码8
关键词Lithium ion batteries Cathode materials LiMn0.6Fe0.4PO4 Carbon coating Electrochemical properties
ISSN号0947-7047
DOI10.1007/s11581-024-05552-y
通讯作者Liu, Guoqiang(879084694@qq.com) ; Liu, Guangyin(liugy13@163.com) ; Wen, Lei(leiwen@imr.ac.cn)
英文摘要Compared with LiFePO4 materials, manganese-based olivine is a promising cathode candidate with high energy and low cost for Li-ion batteries (LIBs). Its rate capability and cyclability challenges still remain even with nano-size and carbon coating. Herein, a high-rate performance is achieved by introducing a novel carbon coating source, poly propylene glycol (PPG 2000). Compared with traditional glucose carbon coating source, it is found that PPG facilitates a highly uniform conductive carbon coating during the carbonized process. Moreover, laser particle size analyzer also suggest that PPG 2000 can act as a highly effective dispersant, which can result in finer primary particles during grinding. Therefore, electronic and ionic conductivity are greatly improved so that the highly Li+ conductive nature of olivine materials can be fully unleashed. The final LiMn0.6Fe0.4PO4/C materials can deliver a capacity of 120 mAhg(-1) even at 10 C rate. This work demonstrates the importance of novel carbon coating source to the active cathode particles and opens upon a new venue for the large-scale fabrication of manganese-based olivine cathode materials.
资助项目National Natural Science Foundation of China[51574081]
WOS研究方向Chemistry ; Electrochemistry ; Physics
语种英语
WOS记录号WOS:001216115500003
出版者SPRINGER HEIDELBERG
资助机构National Natural Science Foundation of China
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Guoqiang; Liu, Guangyin; Wen, Lei
作者单位1.Sichuan Vocat & Tech Coll, Suining 629000, Peoples R China
2.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
3.Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Liu, Guoqiang,Liu, Fushuang,Wang, Qingxiang,et al. Novel carbon coating source for better LiMn0.6Fe0.4PO4/C materials[J]. IONICS,2024:8.
APA Liu, Guoqiang,Liu, Fushuang,Wang, Qingxiang,Liu, Guangyin,&Wen, Lei.(2024).Novel carbon coating source for better LiMn0.6Fe0.4PO4/C materials.IONICS,8.
MLA Liu, Guoqiang,et al."Novel carbon coating source for better LiMn0.6Fe0.4PO4/C materials".IONICS (2024):8.

入库方式: OAI收割

来源:金属研究所

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