Regulating interfacial chemistry and kinetic behaviors of F/Mo co-doping Ni-rich layered oxide cathode for long-cycling lithium-ion batteries over-20 ° C-60 ° C
文献类型：期刊论文
| 作者 | Guan, Siqi1,2; Tao, Lin1; Tang, Pei2,3; Fang, Ruopian5; Wu, Huize2,3; Piao, Nan2; Yang, Huicong2; Hu, Guangjian2,4; Geng, Xin1; Li, Lixiang1 |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
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| 出版日期 | 2024-07-01 |
| 卷号 | 94页码:449-457 |
| 关键词 | Anion -cation co-doping Wide temperature operation Ni-rich layered cathode Phase transition Surface/interface |
| ISSN号 | 2095-4956 |
| DOI | 10.1016/j.jechem.2024.02.064 |
| 通讯作者 | Hu, Guangjian(gjhu@imr.ac.cn) ; An, Baigang(bgan@ustl.edu.cn) ; Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | Ni-rich layered oxide cathodes have shown promise for high-energy lithium -ion batteries (LIBs) but are usually limited to mild environments because of their rapid performance degradation under extreme temperature conditions (below 0 degrees C and above 50 degrees C). Here, we report the design of F/Mo co-doped LiNi 0.8 Co 0.1 Mn 0.1 O 2 (FMNCM) cathode for high-performance LIBs from -20 to 60 degrees C. F - doping with high electronegativity into the cathode surface is found to enhance the stability of surface lattice structure and protect the interface from side reactions with the electrolyte by generating a LiF-rich surface layer. Concurrently, the Mo 6+ doping suppresses phase transition, which blocks Li + /Ni 2+ mixing, and stabilizes lithium -ion diffusion pathway. Remarkably, the FMNCM cathode demonstrates excellent cycling stability at a high cutoff voltage of 4.4 V, even at 60 degrees C, maintaining 90.6% capacity retention at 3 C after 150 cycles. Additionally, at temperatures as low as -20 degrees C, it retains 77.1% of its room temperature capacity, achieving an impressive 97.5% capacity retention after 500 cycles. Such stable operation under wide temperatures has been further validated in practical Ah-level pouch-cells. This study sheds light on both fundamental mechanisms and practical implications for the design of advanced cathode materials for wide-temperature LIBs, presenting a promising path towards high-energy and long-cycling LIBs with temperature adaptability. (c) 2024 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China[51972156] ; National Natural Science Foundation of China[52072378] ; National Natural Science Foundation of China[52102054] ; National Natural Science Foundation of China[51927803] ; National Key R&D Program of China[2022YFB3803400] ; National Key R&D Program of China[2021YFB3800301] ; Shenyang Science and Technology Program[22-322-3-19] ; Youth Fund of the Education Department of Liaoning Province[LJKQZ20222324] ; Outstanding Youth Fund of University of Science and Technology Liaoning[2023YQ11] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001219708100001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China ; Shenyang Science and Technology Program ; Youth Fund of the Education Department of Liaoning Province ; Outstanding Youth Fund of University of Science and Technology Liaoning |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Hu, Guangjian; An, Baigang; Li, Feng |
| 作者单位 | 1.Univ Sci & Technol Liaoning, Inst Energy Mat & Electrochem Res, Anshan 114051, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 4.Shenyang King Power Tech Co Ltd, Shenyang 110016, Liaoning, Peoples R China 5.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia |
| 推荐引用方式 GB/T 7714 | Guan, Siqi,Tao, Lin,Tang, Pei,et al. Regulating interfacial chemistry and kinetic behaviors of F/Mo co-doping Ni-rich layered oxide cathode for long-cycling lithium-ion batteries over-20 ° C-60 ° C[J]. JOURNAL OF ENERGY CHEMISTRY,2024,94:449-457. |
| APA | Guan, Siqi.,Tao, Lin.,Tang, Pei.,Fang, Ruopian.,Wu, Huize.,...&Li, Feng.(2024).Regulating interfacial chemistry and kinetic behaviors of F/Mo co-doping Ni-rich layered oxide cathode for long-cycling lithium-ion batteries over-20 ° C-60 ° C.JOURNAL OF ENERGY CHEMISTRY,94,449-457. |
| MLA | Guan, Siqi,et al."Regulating interfacial chemistry and kinetic behaviors of F/Mo co-doping Ni-rich layered oxide cathode for long-cycling lithium-ion batteries over-20 ° C-60 ° C".JOURNAL OF ENERGY CHEMISTRY 94(2024):449-457. |
入库方式： OAI收割
来源：金属研究所
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