Boosting tribo-catalytic degradation of organic pollutants by BaTiO 3 nanoparticles through metallic coatings
文献类型：期刊论文
| 作者 | Mao, Chenyue1; Zhang, Yi-Chi2,3; Lei, Hua1; Jia, Xuchao1; Chen, Feng4; Yao, Wenqing5; Liu, Peitao2; Chen, Wanping1 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2024-08-01 |
| 卷号 | 663页码:10 |
| 关键词 | Tribo-catalysis Metallic coatings Schottky junction Dye degradation BaTiO3 |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2024.160172 |
| 通讯作者 | Liu, Peitao(ptliu@imr.ac.cn) ; Chen, Wanping(wpchen@whu.edu.cn) |
| 英文摘要 | Recently, tribo-catalysis has emerged as an appealing technology to harvest mechanical energy for environmental remediation. While most investigations have focused on catalyst optimization to enhance tribo-catalytic degradation, here we studied the effects of some metal disks placed on beaker bottoms (named coatings) on the tribo-catalytic degradation by BaTiO 3 (BTO) nanoparticles under magnetic stirring. For 20 mg/L Rhodamine B (RhB) solution, Cr, Cu, and Ti coatings improved the kinetic constants of BTO nanoparticles by 3.1, 3.4, 5.2 folds, respectively. Ti coating was further found to result in 99 % degradation in just 3 h for 50 mg/L RhB solution, and elevate the kinetic constants by 19.1 and 16.6 folds for 20 mg/L methyl orange (MO) and 20 mg/L methylene blue (MB) solutions, respectively. EPR, FL and UV - vis spectroscopy verified that modifying vessel bottom with Ti coating enabled BTO nanoparticles to generate more active species. First -principles calculations of the work functions of Cr, Cu, and Ti surfaces, and the energy -band structure of BTO revealed a decreased electron -hole recombination rate due to the transfer of excited electrons to metallic coatings. These results suggest that modifying vessel bottoms with suitable metallic coatings is a simple, eco-friendly and efficient strategy to boost tribo-catalysis for environmental remediation. |
| 资助项目 | National Natural Science Foundation of China[52236003] ; National Key R & D Program of China[2023YFE0204400] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001237445300001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; National Key R & D Program of China |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Peitao; Chen, Wanping |
| 作者单位 | 1.Wuhan Univ, Sch Phys & Technol, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Guangdong Acad Sci, Inst New Mat, Guangdong Prov Key Lab Met Toughening Technol & Ap, Guangzhou 510650, Peoples R China 5.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, Chenyue,Zhang, Yi-Chi,Lei, Hua,et al. Boosting tribo-catalytic degradation of organic pollutants by BaTiO 3 nanoparticles through metallic coatings[J]. APPLIED SURFACE SCIENCE,2024,663:10. |
| APA | Mao, Chenyue.,Zhang, Yi-Chi.,Lei, Hua.,Jia, Xuchao.,Chen, Feng.,...&Chen, Wanping.(2024).Boosting tribo-catalytic degradation of organic pollutants by BaTiO 3 nanoparticles through metallic coatings.APPLIED SURFACE SCIENCE,663,10. |
| MLA | Mao, Chenyue,et al."Boosting tribo-catalytic degradation of organic pollutants by BaTiO 3 nanoparticles through metallic coatings".APPLIED SURFACE SCIENCE 663(2024):10. |
入库方式： OAI收割
来源：金属研究所
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