Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: structure-function relationships
文献类型：期刊论文
| 作者 | Lu, Xingyu1,2; Qi, Ke1,2; Dai, Xueya1,2; Li, Yunlong1,2; Wang, Di3; Dou, Jing1,2; Qi, Wei1,2 |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2024-07-17 |
| 卷号 | 15期号:28页码:11043-11052 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/d4sc01752h |
| 通讯作者 | Qi, Wei(wqi@imr.ac.cn) |
| 英文摘要 | The biomass-derived HMF oxidation reaction (HMFOR) holds great promise for sustainable production of fine chemicals. However, selective electrooxidation of HMF to high value-added intermediate product 5-formyl-furan-2-formic acid (FFCA) is still challenging. Herein, we report the electrocatalytic HMFOR to selectively produce FFCA using carbon paper (CP) supported polyaniline (PANI) as a catalyst. The PANI/CP non-metallic hybrid catalyst with moderate oxidation capacity exhibitsoptimized FFCA selectivity up to 76% in alkaline media, which has reached the best performance in reported literature studies. Identification and quantification of active sites for the HMFOR are further realized via linking the activity to structural compositions of PANI; both polaronic-type nitrogen (N3) and positively charged nitrogen (N4) species are proved responsible for adsorption and activation of HMF, and the intrinsic activity of N4 is higher than that of N3. The present work provides new physical-chemical insights into the mechanism of the HMFOR on non-metallic catalysts, paving the way for the establishment of structure-function relations and further development of novel electrochemical synthesis systems. The PANI/CP non-metallic catalyst exhibits optimized FFCA selectivity up to 76% inalkaline media. Both N3 and N4 species are proved responsible for adsorption and activation of HMF, and the intrinsic activity of N4 is higher than that of N3. |
| 资助项目 | National Natural Science Foundation of China[22072163] ; National Natural Science Foundation of China[U23A20545] ; National Natural Science Foundation of China[Foundation-BWLCF202113] ; China Baowu Low Carbon Metallurgy Innovation[2023-PY13] ; IMR Innovation Fund |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001250434800001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Baowu Low Carbon Metallurgy Innovation ; IMR Innovation Fund |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Qi, Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Liaoning, Peoples R China 3.Shenyang Pharmaceut Univ, Sch Pharm, 26 Huatuo Rd, Benxi, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Xingyu,Qi, Ke,Dai, Xueya,et al. Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: structure-function relationships[J]. CHEMICAL SCIENCE,2024,15(28):11043-11052. |
| APA | Lu, Xingyu.,Qi, Ke.,Dai, Xueya.,Li, Yunlong.,Wang, Di.,...&Qi, Wei.(2024).Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: structure-function relationships.CHEMICAL SCIENCE,15(28),11043-11052. |
| MLA | Lu, Xingyu,et al."Selective electrooxidation of 5-hydroxymethylfurfural to 5-formyl-furan-2-formic acid on non-metallic polyaniline catalysts: structure-function relationships".CHEMICAL SCIENCE 15.28(2024):11043-11052. |
入库方式： OAI收割
来源：金属研究所
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