Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts
文献类型：期刊论文
| 作者 | Wang, Di1,2; Lu, Xingyu2,3; Xu, Haiyan1; Dou, Jing2,3; Zhang, Xuefei4; Xie, Zailai4; Qi, Wei2,3 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2024-07-09 |
| 页码 | 9 |
| 关键词 | Electrooxidation 5-hydroxymethylfurfural formyl-2-furancarboxylic acid bimetallic catalysts electronic regulation |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.202400449 |
| 通讯作者 | Xu, Haiyan(xhy1020@gmail.com) ; Xie, Zailai(zlxie@fzu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) |
| 英文摘要 | 5-Hydroxymethylfurfural (HMF) is a widely used biomass platform chemical that plays a crucial role in bridging biomass and fossil resources. Electrocatalytic oxidation of HMF provides an efficient way to obtain high-value-added biomass-derived chemicals, among which the intermediate product 5-formyl-2-furan carboxylic acid (FFCA) has attracted considerable attention. However, the weak adsorption ability of monometallic nickel oxide (NiOx) to HMF in neutral electrolyte restricts its further development, resulting in low HMF conversion and FFCA yield. In this study, we successfully constructed a novel nickel oxide-platinum oxide hybrid catalyst supported on carbon felt (NiOx-PtOx/CF), which exhibits an optimized adsorption ability of HMF, leading to the outstanding FFCA yield up to 77 % in the neutral media. The high activity of the NiOx-PtOx/CF catalyst can be attributed to the redistribution of the electrons and the optimization of the electronic structure on the Ni active site due to the introduction of PtOx on NiOx nanosheets. This study offers valuable insights for the design of efficient multicomponent electrocatalysts for electrocatalytic biomass refinery systems. Highly efficient of HMF into FFCA on a NiOx-PtOx/carbon felt composite electrode is achieved at a potential of 1.78 VRHE with high value product of FFCA yield up to 77 %. The high activity of the NiOx-PtOx/CF catalyst can be attributed to the redistribution of the electrons and the optimization of the electronic structure on the Ni active site due to the introduction of PtOx on NiOx nanosheets. image |
| 资助项目 | NSFC of China[22072163] ; NSFC of China[U23A20545] ; Shccig-Qinling Program ; China Baowu Low Carbon Metallurgy Innovation Foundation[BWLCF202113] ; IMR Innovation Fund[2023-PY13] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001264896100001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NSFC of China ; Shccig-Qinling Program ; China Baowu Low Carbon Metallurgy Innovation Foundation ; IMR Innovation Fund |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xu, Haiyan; Xie, Zailai; Qi, Wei |
| 作者单位 | 1.Shenyang Pharmaceut Univ, Sch Pharm, 26 Huatuo Rd,High & New Tech Dev Zone, Benxi 117004, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Di,Lu, Xingyu,Xu, Haiyan,et al. Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts[J]. CHEMCATCHEM,2024:9. |
| APA | Wang, Di.,Lu, Xingyu.,Xu, Haiyan.,Dou, Jing.,Zhang, Xuefei.,...&Qi, Wei.(2024).Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts.CHEMCATCHEM,9. |
| MLA | Wang, Di,et al."Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts".CHEMCATCHEM (2024):9. |
入库方式： OAI收割
来源：金属研究所
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