中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries

文献类型:期刊论文

作者Peng, Zhi1; Yan, Hui2; Zhang, Qingqing1; Liu, Shude5; Jun, Seong Chan3; Poznyak, Sergey4; Guo, Na1; Li, Yuehua1; Tian, Huajun6,7,8; Dai, Lei1
刊名NANO LETTERS
出版日期2024-07-22
卷号24期号:30页码:9137-9146
关键词aqueous Zn-ion batteries anode protectivelayer layered clay ion selection sieving
ISSN号1530-6984
DOI10.1021/acs.nanolett.4c00693
通讯作者Liu, Shude(sdliu@dhu.edu.cn) ; Tian, Huajun(Huajun.Tian@ncepu.edu.cn) ; He, Zhangxing(zxhe@ncst.edu.cn)
英文摘要Uncontrollable dendrite growth and corrosion induced by reactive water molecules and sulfate ions (SO42-) seriously hindered the practical application of aqueous zinc ion batteries (AZIBs). Here we construct artificial solid electrolyte interfaces (SEIs) realized by sodium and calcium bentonite with a layered structure anchored to anodes (NB@Zn and CB@Zn). This artificial SEI layer functioning as a protective coating to isolate activated water molecules, provides high-speed transport channels for Zn2+, and serves as an ionic sieve to repel negatively charged anions while attracting positively charged cations. The theoretical results show that the bentonite electrodes exhibit a higher binding energy for Zn2+. This demonstrates that the bentonite protective layer enhances the Zn-ion deposition kinetics. Consequently, the NB@Zn//MnO2 and CB@Zn//MnO2 full-battery capacities are 96.7 and 70.4 mAh g(-1) at 2.0 A g(-1) after 1000 cycles, respectively. This study aims to stabilize Zn anodes and improve the electrochemical performance of AZIBs by ion-selection sieving.
资助项目National Natural Science Foundation of China[51872090] ; National Natural Science Foundation of China[51772097] ; National Natural Science Foundation of China[52302223] ; Hebei Natural Science Fund for Distinguished Young Scholar[E2019209433] ; Youth Talent Program of Hebei Provincial Education Department[BJ2018020] ; Natural Science Foundation of Hebei Province[E2020209151] ; Natural Science Foundation of Hebei Province[E2022209158] ; Science and Technology Project of Hebei Education Department[SLRC2019028] ; National Research Foundation of Korea (NRF) - Korea government (MIST)[NRF-2019R1A2C2090443] ; Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, Korea)[20013621] ; Beijing Laboratory of New Energy Storage Technology (North China Electric Power University) ; Program of the National Energy Storage Industry-Education Platform
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
WOS记录号WOS:001274536900001
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; Hebei Natural Science Fund for Distinguished Young Scholar ; Youth Talent Program of Hebei Provincial Education Department ; Natural Science Foundation of Hebei Province ; Science and Technology Project of Hebei Education Department ; National Research Foundation of Korea (NRF) - Korea government (MIST) ; Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, Korea) ; Beijing Laboratory of New Energy Storage Technology (North China Electric Power University) ; Program of the National Energy Storage Industry-Education Platform
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Shude; Tian, Huajun; He, Zhangxing
作者单位1.North China Univ Sci & Technol, Sch Chem Engn, Tangshan 063009, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110000, Peoples R China
3.Yonsei Univ, Sch Mech Engn, Seoul 120749, South Korea
4.Belarusian State Univ, Res Inst Phys Chem Problems, Minsk 220030, BELARUS
5.Donghua Univ, Coll Text, Shanghai Frontiers Sci Ctr Adv Text, Shanghai 201620, Peoples R China
6.North China Elect Power Univ, Key Lab Power Stn Energy Transfer Convers & Syst, Minist Educ, Beijing 102206, Peoples R China
7.North China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Beijing, Peoples R China
8.North China Elect Power Univ, Beijing Lab New Energy Storage Technol, Beijing 102206, Peoples R China
推荐引用方式
GB/T 7714
Peng, Zhi,Yan, Hui,Zhang, Qingqing,et al. Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries[J]. NANO LETTERS,2024,24(30):9137-9146.
APA Peng, Zhi.,Yan, Hui.,Zhang, Qingqing.,Liu, Shude.,Jun, Seong Chan.,...&He, Zhangxing.(2024).Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries.NANO LETTERS,24(30),9137-9146.
MLA Peng, Zhi,et al."Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries".NANO LETTERS 24.30(2024):9137-9146.

入库方式: OAI收割

来源:金属研究所

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