Tellurium doped sulfurized polyacrylonitrile nanoflower for high-energy-density, long-lifespan sodium-sulfur batteries
文献类型：期刊论文
| 作者 | Wu, Qiang1; Zhang, Wei1; Qin, Mingsheng1,2; Zhong, Wei1,2; Yan, Hui3; Zhu, Haolin1; Cheng, Shijie1; Xie, Jia1 |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2024-10-01 |
| 卷号 | 129页码:10 |
| 关键词 | Tellurium-doped Nanoflower High-energy-density Ultralong lifetime Sodium-sulfur batteries |
| ISSN号 | 2211-2855 |
| DOI | 10.1016/j.nanoen.2024.110049 |
| 通讯作者 | Xie, Jia(xiejia@hust.edu.cn) |
| 英文摘要 | Sodium-sulfur (Na-S) batteries are promising energy storage devices for large-scale applications due to their high-energy-density and abundant material reserve. However, the practical implementation of room temperature (RT) Na-S batteries faces challenges, including low-energy-density and limited lifespan, particularly attributed to the properties of sulfurized polyacrylonitrile (SPAN). In this study, we address these challenges by introducing tellurium doping into SPAN nanoflowers, enhancing their performance for Na-S batteries. The resulting material exhibits high sulfur loading as well as superior electron and ion transport properties, leading to enhanced redox kinetics and improved battery performance. The tellurium-doped SPAN nanoflower electrode delivers an exceptional composite capacity of 700 mAh g- 1 at 0.1 C and demonstrates stable cycling over 2400 cycles with minimal capacity fade (0.01 % average fading rate). Even under challenging conditions (24.0 mg cm-- 2 , E/ S=5 mg mu L S- 1 , N/P=2.1), the Na-S battery achieves a high areal capacity of 16.1 mAh cm-- 2 , resulting in an impressive energy density of 340.9 Wh kg-1 -1 based on cathode and anode. This work presents a promising approach to designing high-energy-density, long-lifespan RT Na-S batteries, with potential applications for other metal-sulfur battery systems. |
| 资助项目 | National Natural Science Foundation of China[52207237] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001288989300001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xie, Jia |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Technol, Wuhan 430074, Hubei, Peoples R China 2.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Qiang,Zhang, Wei,Qin, Mingsheng,et al. Tellurium doped sulfurized polyacrylonitrile nanoflower for high-energy-density, long-lifespan sodium-sulfur batteries[J]. NANO ENERGY,2024,129:10. |
| APA | Wu, Qiang.,Zhang, Wei.,Qin, Mingsheng.,Zhong, Wei.,Yan, Hui.,...&Xie, Jia.(2024).Tellurium doped sulfurized polyacrylonitrile nanoflower for high-energy-density, long-lifespan sodium-sulfur batteries.NANO ENERGY,129,10. |
| MLA | Wu, Qiang,et al."Tellurium doped sulfurized polyacrylonitrile nanoflower for high-energy-density, long-lifespan sodium-sulfur batteries".NANO ENERGY 129(2024):10. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。