Surface Catalytic Repair for the Efficient Regeneration of Spent Layered Oxide Cathodes
文献类型：期刊论文
| 作者 | Zheng, Nengzhan1; Ji, Haocheng1; Wang, Junxiong1,2; Zhang, Mengtian1; Wei, Linlin3; Shi, Ruyu1; Jia, Kai1,2; Wu, Xinru1; Xiao, Xiao1; Zhuang, Zhaofeng1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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| 出版日期 | 2024-09-24 |
| 卷号 | 146期号:40页码:27819-27829 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.4c10107 |
| 通讯作者 | Li, Bo(boli@mail.tsinghua.edu.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn) ; Zhou, Guangmin(guangminzhou@sz.tsinghua.edu.cn) |
| 英文摘要 | Direct recycling is considered to be the next-generation recycling technology for spent lithium-ion batteries due to its potential economic benefits and environmental friendliness. For the spent layered oxide cathode materials, an irreversible phase transition to a rock-salt structure near the particle surface impedes the reintercalation of lithium ions, thereby hindering the lithium compensation process from fully restoring composition defects and repairing failed structures. We introduced a transition-metal hydroxide precursor, utilizing its surface catalytic activity produced during annealing to convert the rock-salt structure into a layered structure that provides fast migration pathways for lithium ions. The material repair and synthesis processes share the same heating program, enabling the spent cathode and added precursor to undergo a topological transformation to form the targeted layered oxide. This regenerated material exhibits a performance superior to that of commercial cathodes and maintains 88.4% of its initial capacity after 1000 cycles in a 1.3 Ah pouch cell. Techno-economic analysis highlights the environmental and economic advantages of surface catalytic repair over pyrometallurgical and hydrometallurgical methods, indicating its potential for practical application. |
| 资助项目 | Joint Funds of the National Natural Science Foundation of China[U21A20174] ; Guangdong Innovative and Entrepreneurial Research Team Program[2021ZT09L197] ; Shenzhen Science and Technology Program[KQTD20210811090112002] ; Start-up Funds, Interdisciplinary Research and Innovation Fund of Tsinghua Shenzhen International Graduate School ; Tsinghua Shenzhen International Graduate School-Shenzhen Pengrui Young Faculty Program of Shenzhen Pengrui Foundation[SZPR2023007] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001319901300001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Joint Funds of the National Natural Science Foundation of China ; Guangdong Innovative and Entrepreneurial Research Team Program ; Shenzhen Science and Technology Program ; Start-up Funds, Interdisciplinary Research and Innovation Fund of Tsinghua Shenzhen International Graduate School ; Tsinghua Shenzhen International Graduate School-Shenzhen Pengrui Young Faculty Program of Shenzhen Pengrui Foundation |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Bo; Cheng, Hui-Ming; Zhou, Guangmin |
| 作者单位 | 1.Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China 2.Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China 3.Natl Inst Clean & Low Carbon Energy, Beijing 102211, Peoples R China 4.Shenzhen Univ Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen 518055, Peoples R China 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 6.Chinese Acad Sci, Shenzhen Inst Adv Technol, Inst Technol Carbon Neutral, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Nengzhan,Ji, Haocheng,Wang, Junxiong,et al. Surface Catalytic Repair for the Efficient Regeneration of Spent Layered Oxide Cathodes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2024,146(40):27819-27829. |
| APA | Zheng, Nengzhan.,Ji, Haocheng.,Wang, Junxiong.,Zhang, Mengtian.,Wei, Linlin.,...&Zhou, Guangmin.(2024).Surface Catalytic Repair for the Efficient Regeneration of Spent Layered Oxide Cathodes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,146(40),27819-27829. |
| MLA | Zheng, Nengzhan,et al."Surface Catalytic Repair for the Efficient Regeneration of Spent Layered Oxide Cathodes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146.40(2024):27819-27829. |
入库方式： OAI收割
来源：金属研究所
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