中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The effect of Ti/Al ratios on the evolution of precipitates and their effects on tensile properties for Fe3.75Cr1.25NiAl0.6-xTix high entropy alloys

文献类型:期刊论文

作者Ji, Yu1; Zhang, Hongwei1; Pang, Jingyu1; Xing, Zhenqiang1; Zhang, Long1; Zhu, Zhengwang2; Wang, Aimin1; Zhang, Haifeng2
刊名INTERMETALLICS
出版日期2024-12-01
卷号175页码:9
关键词HEAs Microstructure evolution and tensile properties B2 and L2(1) nanoparticles
ISSN号0966-9795
DOI10.1016/j.intermet.2024.108505
通讯作者Zhang, Hongwei(hongweizhang@imr.ac.cn) ; Pang, Jingyu(jypang17s@imr.ac.cn) ; Wang, Aimin(amwang@imr.ac.cn)
英文摘要The work developed a series of novel Co-free high-entropy alloys (HEAs), i.e. Fe3.75Cr1.25NiAl0.6-xTix (x = 0, 0.15, 0.30 and 0.40, molar ratio) HEAs abbreviated as Ti0, Ti0.15, Ti0.30 and Ti0.40, respectively. The effects of Ti/Al ratio (Al partially replaced by Ti) on the microstructure and tensile properties were investigated systematically. The Ti0 HEA contains the FCC phase in dendritic regions and the BCC and B2 phases (BCC/B2) in interdendritic regions. Moreover, the spherical ordered B2 nanoparticles are embedded in the BCC matrix. With increasing the Ti/Al ratio from 0 to 1/3, there is a phase transition from B2-NiAl to L2(1)-Ni2AlTi. Furthermore, the morphology of the nanoparticles evolves from spherical to cuboidal. With further increasing the Ti/Al ratio from 1/3 to 1 and 2, the morphology of nanoparticles evolves from cuboidal back to spherical. In addition, the Ti0.40 HEA has sigma phases besides FCC, BCC, and L2(1) phases. The analysis of tensile properties shows that properly adjusting Ti/Al ratios sharply improves the plasticity and slightly improves the ultimate strength, but only causes a limited decrease in the yield strength. Specifically, the Ti0.15 HEA has a superior combination of strength and plasticity, exhibiting a yield strength of 819 MPa, an ultimate strength of 1113 MPa, and a fracture strain of 13.4 %. The SRO, the solid-solution strengthening, the phase transformation, and the shape of nanoparticles were discussed in detail, which reveals the origins of the excellent tensile properties. In addition, the excessive addition of Ti forms the sigma phase, leading to a serious brittleness. These findings are believed to promote the development of low-cost HEAs with BCC/L21 for practical applications.
资助项目Liaoning Key Research and Development Program, China[2022JH2/101300080] ; Chinese Academy of Sciences, China[ZDBS-LY-JSC023] ; Natural Science Foundation of Liaoning Province, China[2023-BS-012] ; Youth Innovation Promotion Association CAS, China[2021188] ; IMR Innovation Fund, China[2023-PY16]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:001320606700001
出版者ELSEVIER SCI LTD
资助机构Liaoning Key Research and Development Program, China ; Chinese Academy of Sciences, China ; Natural Science Foundation of Liaoning Province, China ; Youth Innovation Promotion Association CAS, China ; IMR Innovation Fund, China
源URL  
专题金属研究所_中国科学院金属研究所
通讯作者Zhang, Hongwei; Pang, Jingyu; Wang, Aimin
作者单位1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
2.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
推荐引用方式
GB/T 7714
Ji, Yu,Zhang, Hongwei,Pang, Jingyu,et al. The effect of Ti/Al ratios on the evolution of precipitates and their effects on tensile properties for Fe3.75Cr1.25NiAl0.6-xTix high entropy alloys[J]. INTERMETALLICS,2024,175:9.
APA Ji, Yu.,Zhang, Hongwei.,Pang, Jingyu.,Xing, Zhenqiang.,Zhang, Long.,...&Zhang, Haifeng.(2024).The effect of Ti/Al ratios on the evolution of precipitates and their effects on tensile properties for Fe3.75Cr1.25NiAl0.6-xTix high entropy alloys.INTERMETALLICS,175,9.
MLA Ji, Yu,et al."The effect of Ti/Al ratios on the evolution of precipitates and their effects on tensile properties for Fe3.75Cr1.25NiAl0.6-xTix high entropy alloys".INTERMETALLICS 175(2024):9.

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来源:金属研究所

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