The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries
文献类型：期刊论文
| 作者 | He, Xin1,2; Zuo, Huai-yang3; Xiao, Ru1,2; Qu, Zhuo-yan1,2; Sun, Zhen-hua1,2; Wang, Bao3; Li, Feng1,2 |
| 刊名 | NEW CARBON MATERIALS
 |
| 出版日期 | 2025-02-01 |
| 卷号 | 40期号:1页码:167-177 |
| 关键词 | Lithium sulfur batteries Low temperature Transition metal sulfides Sulfur conversion kinetics |
| ISSN号 | 2097-1605 |
| DOI | 10.1016/S1872-5805(24)60942-X |
| 通讯作者 | Sun, Zhen-hua(zhsun@imr.ac.cn) ; Wang, Bao(baowang@ipe.ac.cn) ; Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | The use of lithium-sulfur (Li-S) batteries is limited by sulfur redox reactions involving multi-phase transformations, especially at low-temperatures. To address this issue, we report a material (FCNS@NCFs) consisting of nitrogen-doped carbon fibers loaded with a ternary metal sulfide ((Fe, Co, Ni)(9)S-8) for use as the sulfur host in Li-S batteries. This material was prepared using transfer blot filter paper as the carbon precursor, thiourea as the source of nitrogen and sulfur, and FeCl3 center dot 6H(2)O, CoCl2 center dot 6H(2)O and NiCl2 center dot 6H(2)O as the metal ion sources. It was synthesized by an impregnation method followed by calcination. The nitrogen doping significantly increased the conductivity of the host, and the metal sulfides have excellent catalytic activities. Theoretical calculations, and adsorption and deposition experiments show that active sites on the surface of FCNS@NCFs selectively adsorb polysulfides, facilitate rapid adsorption and conversion, prevent cathode passivation and inhibit the polysulfide shuttling. The FCNS@NCFs used as the sulfur host has excellent electrochemical properties. Its initial discharge capacity is 1639.0 mAh g(-1) at 0.2 C and room temperature, and it remains a capacity of 1255.1 mAh g(-1) after 100 cycles. At -20 degrees C, it has an initial discharge capacity of 1578.5 mAh g(-1) at 0.2 C, with a capacity of 867.5 mAh g(-1) after 100 cycles. Its excellent performance at both ambient and low temperatures suggests a new way to produce high-performance low-temperature Li-S batteries. |
| 资助项目 | National Natural Science Foundation of China[52172250] ; Institute of Process Engineering (IPE) Project for Frontier Basic Research[QYJC-2023-06] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001447319600001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Institute of Process Engineering (IPE) Project for Frontier Basic Research |
| 源URL |  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Sun, Zhen-hua; Wang, Bao; Li, Feng |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Xin,Zuo, Huai-yang,Xiao, Ru,et al. The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries[J]. NEW CARBON MATERIALS,2025,40(1):167-177. |
| APA | He, Xin.,Zuo, Huai-yang.,Xiao, Ru.,Qu, Zhuo-yan.,Sun, Zhen-hua.,...&Li, Feng.(2025).The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries.NEW CARBON MATERIALS,40(1),167-177. |
| MLA | He, Xin,et al."The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries".NEW CARBON MATERIALS 40.1(2025):167-177. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。