Photocatalysis regulated surface-enhanced Raman scattering for rapid detection and differentiation of semiconductor minerals
文献类型：期刊论文
| 作者 | Qi, Peng1,2; Jiang, Huihuang3; Chen, Peipei3; Mao, Haimei4; Zeng, Yan1,2; Zhao, Hongliang4; Wang, Peng1,2 |
| 刊名 | MICROCHEMICAL JOURNAL
 |
| 出版日期 | 2025-12-01 |
| 卷号 | 219页码:10 |
| 关键词 | Mineralogical detection MB@Au@Fe 3 O 4 nanoprobe Photocatalysis SERS Microbiologically influenced corrosion |
| ISSN号 | 0026-265X |
| DOI | 10.1016/j.microc.2025.116306 |
| 通讯作者 | Qi, Peng(qipeng@qdio.ac.cn) ; Jiang, Huihuang(huihuang111000@163.com) ; Wang, Peng(wangpeng@qdio.ac.cn) |
| 英文摘要 | Background: Mineralogical detection faces challenges due to the diversity of minerals, analytical complexity, variable conditions, and limitations in equipment portability and cost. Traditional techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM) offer elemental and structural characterization but face limitations in portability and cost, and often require sophisticated sample preparation. Raman spectroscopy, a non-destructive and highly selective analytical technique, is limited by weak signals and overlapping peaks in complex samples. To address these limitations, we introduce a novel surface-enhanced Raman spectroscopy (SERS) nanoprobe, MB@Au@Fe3O4, designed for the detection of semiconductor minerals. Results: In this paper, a surface-enhanced Raman spectroscopy (SERS) probe, methylene blue (MB)-Au@Fe3O4 core-shell (MB@Au@Fe3O4) composite, was designed to detect and identify semiconductor minerals. The nanoprobe utilized MB as the SERS signal molecule and Au as the SERS enhancement substrate, while incorporated magnetic Fe3O4 to drive the nanoprobe proximity to the reaction interface. The nanoprobe utilizes photocatalytic degradation of MB to transduce semiconductor activity into recordable SERS signal changes, enabling rapid and sensitive detection of FeS, FeS2, and FeOOH. Experiments demonstrated that the nanoprobe successfully differentiates these minerals based on their intrinsic photocatalytic capabilities, with high sensitivity and specificity. Moreover, the MB@Au@Fe3O4 nanoprobe was applied for in situ inspection of corrosion products beneath biofilms, demonstrating its potential for practical applications in complex environments. Significance and novelty: The MB@Au@Fe3O4 nanoprobe offers a practical and innovative solution for the rapid and sensitive detection of semiconductor minerals in complex environments. This approach overcomes the limitations of traditional techniques, providing enhanced sensitivity and specificity without the need for largescale equipment or complex sample preparation. The findings highlight the potential for on-site detection and monitoring of semiconductor minerals in various real-world applications. |
| 资助项目 | National Natural Science Foundation of China[42376208] ; Guangxi Science and Technology Program[Guike AA24263064] ; Science & Technology Program of Nantong[JC2023083] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001631484100003 |
| 出版者 | ELSEVIER |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/204387]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 通讯作者 | Qi, Peng; Jiang, Huihuang; Wang, Peng |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Adv Marine Mat, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Minist Nat Resources, Nantong Marine Ctr, Nantong 226002, Peoples R China 4.Hainan Acad Inspect & Testing, Key Lab Qual Safe Evaluat & Res Degradable Mat, State Adm Market Regulat, Haikou 570203, Hainan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Peng,Jiang, Huihuang,Chen, Peipei,et al. Photocatalysis regulated surface-enhanced Raman scattering for rapid detection and differentiation of semiconductor minerals[J]. MICROCHEMICAL JOURNAL,2025,219:10. |
| APA | Qi, Peng.,Jiang, Huihuang.,Chen, Peipei.,Mao, Haimei.,Zeng, Yan.,...&Wang, Peng.(2025).Photocatalysis regulated surface-enhanced Raman scattering for rapid detection and differentiation of semiconductor minerals.MICROCHEMICAL JOURNAL,219,10. |
| MLA | Qi, Peng,et al."Photocatalysis regulated surface-enhanced Raman scattering for rapid detection and differentiation of semiconductor minerals".MICROCHEMICAL JOURNAL 219(2025):10. |
入库方式： OAI收割
来源：海洋研究所
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