Electrosynthesis of poly(3,4-ethylenedithiathiophene) in an ionic liquid and its electrochemistry and electrochromic properties
文献类型：期刊论文
| 作者 | Lu Baoyang; Zhang Shimin; Qin Leiqiang; Chen Shuai; Zhen Shijie; Xu Jingkun |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2013 |
| 卷号 | 106期号:9页码:201-208 |
| 关键词 | Poly(3,4-ethylenedithiathiophene) Electropolymerization Ionic liquids Redoping Electrochromics |
| ISSN号 | 0013-4686 |
| 英文摘要 | We herein report the electrosynthesis of the all-sulfur analog of PEDOT, poly(3,4-ethylenedithiathiophene) (PEDTT), in air and moisture stable ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF(6)). The as-obtained PEDTT film was studied by FT-IR, SEM, GPC, UV-vis spectroscopy, fluorescence and thermal analysis, respectively. Electrochemistry results demonstrated that PEDTT film could be further doped by cyclic voltammetry to substantially improve its doping level. Besides, PEDTT exhibits electrochromic nature with its color changing from golden brown in its reduced form to grass green upon oxidation. By further investigation, PEDTT was also found to reveal favorable coloration efficiency of 127 cm(2) C-1 comparable to PEDOT, low switching voltages and favorable electroactivity and stability. (c) 2013 Elsevier Ltd. All rights reserved. |
| 学科主题 | Electrochemistry |
| 收录类别 | SCI |
| WOS记录号 | WOS:000323192400026 |
| 公开日期 | 2013-11-07 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2634]  |
| 专题 | 新疆理化技术研究所_环境科学与技术研究室 |
| 作者单位 | Jiangxi Sci & Technol Normal Univ, Sch Pharm, Nanchang 330013, Peoples R China;Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China;Chinese Acad Sci, Lab Environm Sci & Technol, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu Baoyang,Zhang Shimin,Qin Leiqiang,et al. Electrosynthesis of poly(3,4-ethylenedithiathiophene) in an ionic liquid and its electrochemistry and electrochromic properties[J]. ELECTROCHIMICA ACTA,2013,106(9):201-208. |
| APA | Lu Baoyang,Zhang Shimin,Qin Leiqiang,Chen Shuai,Zhen Shijie,&Xu Jingkun.(2013).Electrosynthesis of poly(3,4-ethylenedithiathiophene) in an ionic liquid and its electrochemistry and electrochromic properties.ELECTROCHIMICA ACTA,106(9),201-208. |
| MLA | Lu Baoyang,et al."Electrosynthesis of poly(3,4-ethylenedithiathiophene) in an ionic liquid and its electrochemistry and electrochromic properties".ELECTROCHIMICA ACTA 106.9(2013):201-208. |
入库方式： OAI收割
来源：新疆理化技术研究所
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